Unique Ionic Iodine Atom Transfer Cyclization:  A New Route to Iodomethylated Pyrrolidine Derivatives from γ-Iodoolefin and Chloramine-T

Pyrrolidines and bicyclic pyrrolidine derivatives can effectively be synthesized from γ-iodoolefins using commercially available chloramine-T (CT) as a nitrogen source. The cyclization proceeds with high stereoselectivity via a cyclic iodonium intermediate.

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PID https://www.doi.org/10.1021/ol026020i
PID https://www.doi.org/10.1021/ol026020i.s001
URL https://academic.microsoft.com/#/detail/2952767656
URL http://dx.doi.org/10.1021/ol026020i
URL https://pubs.acs.org/doi/pdf/10.1021/ol026020i
URL https://www.ncbi.nlm.nih.gov/pubmed/12049527
URL https://pubs.acs.org/doi/10.1021/ol026020i
URL https://figshare.com/articles/journal_contribution/Unique_Ionic_Iodine_Atom_Transfer_Cyclization_A_New_Route_to_Iodomethylated_Pyrrolidine_Derivatives_from_-Iodoolefin_and_Chloramine-T/3742935
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Access Right Open Access
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Author Minakata, Satoshi
Author Kano, Daisuke
Author Oderaotoshi, Yoji
Author Komatsu, Mitsuo
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Collected From figshare; Datacite; Crossref; Microsoft Academic Graph
Hosted By Organic Letters; figshare
Journal Organic Letters, 4, null
Publication Date 2016-08-20
Publisher American Chemical Society (ACS)
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::d47d7cf61f004b7959fc93f458937198
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Last Updated 24 December 2020, 22:32 (CET)
Created 24 December 2020, 22:32 (CET)