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Redirection of Oxidation Reactions by a Polyoxomolybdate: Oxydehydrogenation...
Redirection of Oxidation Reactions by a Polyoxomolybdate: Oxydehydrogenation Instead of Oxygenation of Alkanes with tert-Butylhydroperoxide in Acetic Acid -
Catalytic Reductive Coupling of 9-Bromofluorene
The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel... -
Optical Resolution of (±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine as a Ch...
(±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine, prepared from benzil and ammonium acetate, was optically resolved as a chiral framework for... -
Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction
Inverse electron-demand aza Diels−Alder reaction of aldimine with enol ethers proceeded under the influence of a phosphoric acid diester, derived from (R)-BINOL, to give... -
Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synt...
A new type of chiral bicycle imidazole nucleophilic catalyst was rationally designed, facilely synthesized, and successfully applied in an asymmetric Steglich rearrangement with... -
r37980778c78--adcc2831682b7bb0465201a2ba3f38b4
We have designed and synthesized a HAB-based receptor with six ethereal oxygens on one face of the central benzene ring by a trimerization of a diarylacetylene in which the... -
Inorganic Single Wall Nanotubes of SbPS<sub>4</sub><sub>-</sub><i><sub>x</sub...
A new ternary member, SbPS4, has been added to the growing inorganic nanotube family. This material naturally forms bundles of long, single wall nanotubes. -
High and Selective CO<sub>2</sub> Uptake in a Cobalt Adeninate Metal−Organic ...
High and Selective CO2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores -
An Undoped, Single-Phase Oxide Photocatalyst Working under Visible Light
A novel photocatalyst, PbBi2Nb2O9 has been discovered that shows high activities for degradation of organic pollutants, generation of photocurrent, and water decomposition into... -
r37980778c78--c2e058e9f2f01b1c25af7d03fb1f0979
The structure of {p-C6H4[CH2OCH2C(pz)3]2[Ru(p-cymene)]2}Cl4·14H2O (pz = pyrazolyl ring) contains a one-dimensional water chain associated into an inorganic (carbon-free) layer... -
Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate
A new type of cyano-bridged Co−W bimetallic assembly, CsI[{CoII(3-cyanopyridine)2}{WV(CN)8}]·H2O was synthesized. This compound exhibited a temperature-induced phase transition... -
r37980778c78--8304577be7138c775e0dbafe67ac507e
(±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine, prepared from benzil and ammonium acetate, was optically resolved as a chiral framework for... -
A Linear, Four-Spin Mn(II)−Nitronyl−Nitroxide-Substituted Phosphine Oxide Sys...
A Linear, Four-Spin Mn(II)−Nitronyl−Nitroxide-Substituted Phosphine Oxide System Exhibiting Both Antiferro- and Ferromagnetic Interactions§ -
Ruthenium-Catalyzed [2 + 2] Cycloadditions of Bicyclic Alkenes with Alkynyl P...
Ruthenium-catalyzed [2 + 2] cycloadditions of bicyclic alkenes with alkynyl phosphonates were investigated. The phosphonate moieties were found to be compatible with the... -
Lewis Acid-Promoted Conjugate Addition of Dienol Silyl Ethers to Nitroalkenes...
A novel γ-selective conjugate addition of 1-silyl-substituted dienol ethers to nitroalkenes activated by Lewis acids has been developed. The resulting α,β-unsaturated... -
Novel Amphiphilic Conetworks Composed of Telechelic Poly(ethylene oxide) and ...
Amphiphilic conetworks (APCNs) containing covalently bonded hydrophilic poly(ethyleneoxide) (PEO) and hydrophobic polyisobutylene (PIB) have been synthesized by chain end... -
Generation and Characterization of Four Dilutions of Diesel Engine Exhaust fo...
Exposure atmospheres for a rodent inhalation toxicology study were generated from the exhaust of a 2000 Cummins ISB 5.9L diesel engine coupled to a dynamometer and operated on a... -
Oxidative Aromatization of 9,10-Dihydroanthracenes Using Molecular Oxygen Pro...
Substituted 9,10-dihydroanthracenes were oxidatively aromatized to the corresponding anthracenes effectively by using molecular oxygen as an oxidant and activated carbon (Darco... -
r37980778c78--fb2c9e56a071472b52b76dc212338718
The convergent total synthesis of brevetoxin B (1) has been achieved. The intramolecular allylation of the O,S-acetal 20, prepared from the α-chlorosulfide 17 and the alcohol 5,...
