Catalytic Reductive Coupling of 9-Bromofluorene

The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel cluster Ru4(μ3-OMe)(μ3-OH)(μ-Br)2(CO)10, which is found to be even more catalytically active. Further reaction of this cluster with bromofluorene gives another novel cluster, Ru4(μ4-O)(μ-Br)6(CO)8, which is inactive.

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PID https://www.doi.org/10.1021/om050850t.s002
URL https://figshare.com/articles/dataset/Catalytic_Reductive_Coupling_of_9_Bromofluorene/3246241
URL https://figshare.com/articles/Catalytic_Reductive_Coupling_of_9_Bromofluorene/3246241
URL http://dx.doi.org/10.1021/om050850t.s002
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Author Sridevi, Venugopal Shanmugham
Author Leong, Weng Kee
Author Zhu, Yinghuai
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Collected From figshare
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Publication Date 2016-01-01
Publisher Figshare
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::50a8537024739d6e99c5060cea627645
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Last Updated 11 January 2021, 00:19 (CET)
Created 11 January 2021, 00:19 (CET)