Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synthesis, and Successful Application in Asymmetric Steglich Rearrangement

A new type of chiral bicycle imidazole nucleophilic catalyst was rationally designed, facilely synthesized, and successfully applied in an asymmetric Steglich rearrangement with good to excellent yield and enantioselectivity at ambient temperature. Moreover, it can be easily recycled with almost no reduction of catalytic efficiency. This is the first example for the successful chiral imidazole nucleophilic catalyst without H-bonding assistance.

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PID https://www.doi.org/10.1021/ja109069k.s001
URL http://dx.doi.org/10.1021/ja109069k.s001
URL https://figshare.com/articles/Chiral_Bicycle_Imidazole_Nucleophilic_Catalysts_Rational_Design_Facile_Synthesis_and_Successful_Application_in_Asymmetric_Steglich_Rearrangement/2712649
URL https://figshare.com/articles/dataset/Chiral_Bicycle_Imidazole_Nucleophilic_Catalysts_Rational_Design_Facile_Synthesis_and_Successful_Application_in_Asymmetric_Steglich_Rearrangement/2712649
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Access Right Open Access
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Author Zhang, Zhenfeng
Author Xie, Fang
Author Jia, Jia
Author Zhang, Wanbin
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Collected From figshare
Hosted By figshare
Publication Date 2016-02-24
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Language English
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::e79e6ea29c9bd57de7111b0bbd989e43
Author jsonws_user
Last Updated 2 January 2021, 22:10 (CET)
Created 2 January 2021, 22:10 (CET)