Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co

The disproportionation of dicobalt octacarbonyl induced by the free carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and the X-ray characterization of the...

By using an achiral (4-carboxynaphthalen-1-yl)­phosphonic acid (4-cnappH3), compound Co2(4-cnapp)­(OH)­(H2O)2 (1) is isolated crystallizing in orthorhomibic space group P212121....

Nitrile hydratases (NHases) are thiolate-ligated Fe(III)- or Co(III)- containing enzymes, which convert nitriles to the corresponding amide under mild conditions. Proposed NHase...

Abbreviations: SD, standard deviation; BMI, body mass index; WC, waist circumference; WHtR, waist-to-height ratio; HDL-c, high-density lipoprotein cholesterol; LDL-c,...

The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid...

Metal–organic frameworks are among the most promising materials for industrial gas separations, including the removal of carbon dioxide from natural gas, although substantial...

The magnetic properties of Co(N3)2(4acpy)2 have been thoroughly reexamined on both powder and well-oriented single crystal samples. This azido-bridged cobalt compound of (4, 4)...

A Co­(II)–Ti­(IV) heterometallic approach is successfully adopted to synthesize charge-neutral metal–organic frameworks based on oxo-centered trinuclear cluster and linear...

Cobalt­(III)-promoted C–H activation reactions have witnessed explosive progress in recent few years. However, the roles played by the various spin states of Co­(III) center in...

Comparison of trace element contents in toenails of males and females.

To investigate the influence of the size of the aromatic chelate ligands on the frameworks of metal dicarboxylate polymers, four new coordination compounds...

By introducing an amino substituent group on the dicarboxylate ligand, a porous doubly pillared-layer framework [Co2(abdc)2(bpy)2]·8DMF (2; abdc = 2-amino-1,4-benzene...

The exchange mechanism and magnetic structure of the organic–inorganic layered molecule-based magnet [Co2(bta)]n (1) (H4bta =1,2,4,5-benzenetetracarboxylic acid) have been...

In an effort to probe the structure of a group Bb metallo-β-lactamase, Co(II)-substituted ImiS was prepared and characterized by electronic absorption, NMR, and EPR...

Trace element contents in toenails of inactive and active men and women.

Two 3D isostructural metal–organic frameworks with 1D ferrimagnetic chains, formulated as [M3(L)­(μ3-OH)2(H2O)4] [H4L = (1,1′:4′,1″-terphenyl)-2′,3,3″,5′-tetracarboxylic acid,...

Two new fluorinated microporous cobalt phosphates, (H2en)0.5[F0.25Co(H0.5PO4)0.5(PO4)0.5]·0.25H2O (1) and (H2en)0.5[Fx(H2O)0.25-xCo(HPO3)x(PO4)1-x]·0.25H2O (x = 0.17; 2), have...

Co3(SO4)3(OH)2[enH2]: A New S = 3/2 Kagome-Type Layered Sulfate with a Unique Connectivity

IC50s and % inhibition of assayed metal complexes.