r37980778c78--f6c5a05850f275f705cbd023ba2ff0b5

The disproportionation of dicobalt octacarbonyl induced by the free carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and the X-ray characterization of the cyclohexane solvate of the resulting cobalt carbonyl N-heterocyclic carbene salt, [Co(CO)3(IMes)2]+[Co(CO)4] -ยท1/4C6H12, is reported. The crystal structure represents the first example of a [Co(CO)3(L)2][Co(CO)4] disproportionate salt reported to date.

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PID https://www.doi.org/10.1021/ic062368o.s001
URL https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_Novel_Cobalt_Carbonyl_N_Heterocyclic_Carbene_Salt_Crystal_Structure_of_Co_CO_sub_3_sub_IMes_sub_2_sub_sup_sup_Co_CO_sub_4_sub_sup_sup_/3018367
URL https://figshare.com/articles/Synthesis_and_Characterization_of_a_Novel_Cobalt_Carbonyl_N_Heterocyclic_Carbene_Salt_Crystal_Structure_of_Co_CO_sub_3_sub_IMes_sub_2_sub_sup_sup_Co_CO_sub_4_sub_sup_sup_/3018367
URL http://dx.doi.org/10.1021/ic062368o.s001
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Access Right Open Access
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Collected From figshare
Hosted By figshare
Publication Date 2016-02-29
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Language UNKNOWN
Resource Type Dataset
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::f6c5a05850f275f705cbd023ba2ff0b5
Author jsonws_user
Last Updated 13 January 2021, 12:56 (CET)
Created 13 January 2021, 12:56 (CET)