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Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and S...
The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with... -
Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...
The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular... -
Synthesis, Structural Characterization, and Readsorption Behavior of a Solid ...
Members of the new solid solution aluminum phosphite/ ethylenediphosphonate series, Al2(O3PC2H4PO3)1-x(HPO3)2x2F2·H2O (0 ≤ x ≤ 0.32), have been prepared and fully characterized.... -
Current-Induced Metallic State in an Organic (EDT-TSF)<sub>2</sub>GaCl<sub>4<...
A newly prepared organic conductor, (EDT-TSF)2GaCl4, shows considerable nonlinear conductance in the insulating state below 20 K, and a metallic state is restored by the... -
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocycl...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is... -
Catalytic Reductive Coupling of 9-Bromofluorene
The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel... -
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbony...
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of... -
Topotactic Oxidative and Reductive Control of the Structures and Properties o...
Topotactic modification, by both oxidation and reduction, of the composition, structures, and magnetic properties of the layered oxychalcogenides Sr4Mn3O7.5Cu2Ch2 (Ch = S, Se)... -
r37980778c78--6aa49dd0ac4cda71eae14d5dde9106fc
A new layered aluminophosphate, [C6N3H17][Al2(HPO4)(PO4)2] (denoted AlPO−CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the... -
Primers used in this study.
a Liu et al., 2011 [19]. b Ji et al., 2007 [20]. c Wei et al., 2010 [21]. d Noteborn et al., 2013 [22]. *Positions correspond to: IBDV (JQ684022), IBV (KJ425500), AEV... -
Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction
Inverse electron-demand aza Diels−Alder reaction of aldimine with enol ethers proceeded under the influence of a phosphoric acid diester, derived from (R)-BINOL, to give... -
Unprecedented Tunable Tetraazamacrocycles
Novel nitrogen-bridged aza[14]cyclophanes with fine-tuned cavities have been synthesized by nucleophilic aromatic substitution of 1,5-difluoro-2,4-dinitrobenzene with... -
Polybrominated Dibenzo-<i>p</i>-dioxins, Dibenzofurans, and Diphenyl Ethers i...
Human adipose samples collected in Tokyo, Japan in 1970 and 2000 were analyzed for the presence of polybrominated dibenzo-p-dioxins (PBDDs), dibenzofurans (PBDFs), and diphenyl... -
r37980778c78--e63bc64b93e734e9841b9fd1551f176b
An Icosahedral Array of Methyl Groups Supported by an Aromatic Borane Scaffold: The [closo-B12(CH3)12]2- Ion -
Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synt...
A new type of chiral bicycle imidazole nucleophilic catalyst was rationally designed, facilely synthesized, and successfully applied in an asymmetric Steglich rearrangement with... -
r37980778c78--f94d10d2f9eb3bb5aae9f6cbe5464900
Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation -
High and Selective CO<sub>2</sub> Uptake in a Cobalt Adeninate Metal−Organic ...
High and Selective CO2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores -
r37980778c78--6084b7b843db6a80cbba609e46d3b6f8
Tertiary Aromatic Amide for Memory of Chirality: Access to Enantioenriched α-Substituted Valine -
r37980778c78--c2e058e9f2f01b1c25af7d03fb1f0979
The structure of {p-C6H4[CH2OCH2C(pz)3]2[Ru(p-cymene)]2}Cl4·14H2O (pz = pyrazolyl ring) contains a one-dimensional water chain associated into an inorganic (carbon-free) layer... -
Diastereoselective Oxidative Carbon−Carbon Bond Formation via Silyl Bis-enol ...
Diisopropylsilyl bis-enol ethers are shown to be powerful intermediates for the diastereoselective dimerization and cross-coupling of cyclic ketones. The trends observed for the...
