1,819 items found

Groups: figshare Tags: Biochemistry Physical Sciences not elsewhere classified

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  • dataset

    Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and S...

    The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with...
  • dataset

    Intermolecular Activation of Hydrocarbon C−H Bonds Initiated by the Tungsten ...

    trans-CpW(NO)(CH2EMe3)(H)(PMe3) (E = C, Si) complexes can be prepared by the hydrogenation at 1 atm of the appropriate CpW(NO)(CH2EMe3)2 precursor in the presence of a slight...
  • dataset

    Electronic Tuning of Mg<sub>2</sub>Cu<sub>6</sub>Ga<sub>5</sub>. A Route to C...

    Studies of Mg2Cu6Ga5 reveal that this compound contains incomplete Bergman clusters in its structure and shows a pseudogap and empty bonding states just above the Fermi energy...
  • dataset

    Synthesis and Structure of Sr<sub>3</sub>GaN<sub>3</sub> and Sr<sub>6</sub>Ga...

    Two new strontium gallium nitrides were obtained as single crystals by reaction in molten Na. Black Sr3GaN3 is isostructural with its transition metal analogues, Sr3MnN3,...
  • dataset

    Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...

    The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular...
  • dataset

    Media 2: Direct visualization of a polariton resonator in the THz regime

    Originally published in Optics Express on 31 May 2004 (oe-12-11-2387)
  • dataset

    r37980778c78--bc001d315c0aa0c725a9c9c3ca539c9b

    Color tuning and switching of the solid-state luminescence of organic materials are attractive subjects for both the fundamental research and practical applications such as...
  • dataset

    r37980778c78--77decee5d844927dd218e6ce40954484

    We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine...
  • dataset

    Quantitation of Twelve Metals in Tequila and Mezcal Spirits as Authenticity P...

    In this paper the differentiation of silver, gold, aged and extra-aged tequila and mezcal has been carried out according to their metal content. Aluminum, barium, calcium,...
  • dataset

    Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...

    This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),...
  • dataset

    Revisiting the Thermal Decomposition of Layered γ-Titanium Phosphate and Stru...

    The thermal transformations of γ-titanium phosphate, Ti(PO4)(H2PO4)·2H2O, have been studied by thermal analyses (thermogravimetry (TG) and differential thermal analysis (DTA))...
  • dataset

    r37980778c78--63d348228602793543956144b74b0720

    In this novel motif, scandium atoms define infinite parallel chains of alternate trans-face-sharing cubes and pairs of square antiprisms in which each polyhedron is also...
  • dataset

    Photoactivation of Ruthenium Olefin Metathesis Initiators

    UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro−trans-dichloro photoisomerization. The enhanced activity of the trans...
  • dataset

    Full Miscibility of Disk- and Rod-Shaped Mesogens in the Nematic Phase

    Mesogens containing rod-shaped moieties as well as one disk-shaped group exhibit nematic phase behavior and are entirely miscible with rod- and disk-shaped mesogens in the...
  • dataset

    Tuning the Optical Properties of Aryl-Substituted Dispirofluorene-Indenofluor...

    Two families of positional isomers of dispirofluorene-indenofluorene substituted by phenyl groups at the 2,7-positions of the fluorene moieties present drastically different...
  • dataset

    Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Tr...

    Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co
  • dataset

    Long-Range Ordered Magnet of a Charge-Transfer Ru<sub>2</sub><sup>4+</sup>/TC...

    Two isostructural 2D assemblies composed of [Ru2(O2CCF3)4] and TCNQ or TCNQF4 in a 2:1 ratio were synthesized:  [{Ru2(O2CCF3)4}2TCNQ]·3(p-xylene) (1b) and...
  • dataset

    Current-Induced Metallic State in an Organic (EDT-TSF)<sub>2</sub>GaCl<sub>4<...

    A newly prepared organic conductor, (EDT-TSF)2GaCl4, shows considerable nonlinear conductance in the insulating state below 20 K, and a metallic state is restored by the...
  • dataset

    r37980778c78--f6c5a05850f275f705cbd023ba2ff0b5

    The disproportionation of dicobalt octacarbonyl induced by the free carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and the X-ray characterization of the...
  • dataset

    Effect of 2,6-Disubstituted Aryl Groups on Acyclic Conformation:  Preference ...

    Multiple X-ray crystallographic and 1H NMR spectroscopic studies demonstrate that 2,6-disubstituted aryl groups exert a strong effect on acyclic conformation, inducing the...