r37980778c78--63d348228602793543956144b74b0720

In this novel motif, scandium atoms define infinite parallel chains of alternate trans-face-sharing cubes and pairs of square antiprisms in which each polyhedron is also centered by an M atom (M = Ru, Os). These chains are further linked into a three-dimensional structure by Sc(Te2Te4/2) octahedra. Physical property measurements show Sc14Ru3Te8 to be metallic and Pauli-paramagnetic, consistent with the results of extended Hückel band structure calculations. Matrix effects are evident in the dimensions within the chains. The major interactions are Sc−M and Sc−Te.

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PID https://www.doi.org/10.1021/ja0291540.s003
URL http://dx.doi.org/10.1021/ja0291540.s003
URL https://figshare.com/articles/dataset/Remarkable_Metal-Rich_Ternary_Chalcogenides_Sc_sub_14_sub_M_sub_3_sub_Te_sub_8_sub_M_Ru_Os_/3647511
URL https://figshare.com/articles/Remarkable_Metal-Rich_Ternary_Chalcogenides_Sc_sub_14_sub_M_sub_3_sub_Te_sub_8_sub_M_Ru_Os_/3647511
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Access Right Open Access
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Collected From figshare
Hosted By figshare
Publication Date 2016-08-18
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Language UNKNOWN
Resource Type Dataset
keyword H ückel band structure calculations
system:type dataset
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::63d348228602793543956144b74b0720
Author jsonws_user
Last Updated 13 January 2021, 17:09 (CET)
Created 13 January 2021, 17:09 (CET)