The First Tetrathiafulvalene− σ−Polynitrofluorene Diads: Low HOMO−LUMO Gap, Amphoteric Redox Behavior, and Charge Transfer Properties

The synthesis, solution redox behavior, EPR, and intramolecular charge transfer properties of novel donor−acceptor diads of TTF−σ−A type (TTF = substituted tetrathiafulvalene, σ = saturated spacer, A = polynitrofluorene acceptor) are reported. The HOMO−LUMO gap for compound 6 is as small as 0.3 eV, and spectroelectrochemical experiments reveal its electrochromic behavior in the near-IR region.

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PID https://www.doi.org/10.1021/ol015581r.s001
URL https://figshare.com/articles/journal_contribution/The_First_Tetrathiafulvalene__Polynitrofluorene_Diads_Low_HOMO_LUMO_Gap_Amphoteric_Redox_Behavior_and_Charge_Transfer_Properties/3738720
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Access Right Open Access
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Author Perepichka, Dmitrii F.
Author Bryce, Martin R.
Author McInnes, Eric J. L.
Author Zhao, Jing P.
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Collected From figshare
Hosted By figshare
Publication Date 2016-08-20
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Language English
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::65ee63cbd894757ab6de782740caf0bc
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Last Updated 27 December 2020, 03:08 (CET)
Created 27 December 2020, 03:08 (CET)