r37980778c78--5ff34496ad0852736827049274b83b40

The total synthesis of VM55599, a natural metabolite of Penicillium sp. IMI332995, has been achieved via an intramolecular Diels−Alder cycloaddition of a reverse isoprene moiety across an azadiene system. The diastereoselectivity of the intramolecular Diels−Alder cycloaddition has biogenetic implications and is discussed in the context of the biogenetic relationship of VM55599 to the paraherquamides.

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PID https://www.doi.org/10.1021/ja993791h.s001
URL https://figshare.com/articles/journal_contribution/Total_Synthesis_of_VM55599_Utilization_of_an_Intramolecular_Diels_Alder_Cycloaddition_of_Potential_Biogenetic_Relevance/3678021
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Collected From figshare
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Publication Date 2016-08-19
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Language UNKNOWN
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::5ff34496ad0852736827049274b83b40
Author jsonws_user
Last Updated 23 December 2020, 10:42 (CET)
Created 23 December 2020, 10:42 (CET)