r37980778c78--3125595b8d537b0cd4569b2790bd7530

The intramolecular Pauson−Khand reaction of 2-oxazolone derivatives with a suitable pentynyl appendage exclusively gave the corresponding 4-hydroxy-6-substituted-9-oxa-1-azatricyclo[6.2.1.05,11]undec-5-en-7,10-diones. Based on this newly developed Pauson−Khand reaction of 2-oxazolone-alkyne derivatives, the first total synthesis of (±)-8α-hydroxystreptazolone was accomplished in a highly stereoselective manner.

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PID https://www.doi.org/10.1021/ol020189e.s001
URL https://figshare.com/articles/journal_contribution/Total_Synthesis_of_-8_-Hydroxystreptazolone/3741978
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Collected From figshare
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Publication Date 2016-08-20
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::3125595b8d537b0cd4569b2790bd7530
Author jsonws_user
Last Updated 24 December 2020, 21:52 (CET)
Created 24 December 2020, 21:52 (CET)