Electrophilicity and Nucleophilicity Index for Radicals

Radicals can be regarded as electrophilic/nucleophilic, depending on their tendency to attack sites of relatively higher/lower electron density. In this paper, an electrophilicity scale, global as well as local, and a nucleophilicity scale for 35 radicals is reported. The global electrophilicity scale correlates well with the nucleophilicity scale, suggesting that these concepts are inversely related.

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PID https://www.doi.org/10.1021/ol071038k
PID https://www.doi.org/10.1021/ol071038k.s002
PID https://www.doi.org/10.1021/ol071038k.s001
URL http://www.ncbi.nlm.nih.gov/pubmed/17559221
URL https://core.ac.uk/display/55881213
URL https://figshare.com/articles/journal_contribution/Electrophilicity_and_Nucleophilicity_Index_for_Radicals/2998645
URL https://figshare.com/articles/journal_contribution/Electrophilicity_and_Nucleophilicity_Index_for_Radicals/2998654
URL https://pubs.acs.org/doi/pdf/10.1021/ol071038k
URL https://pubs.acs.org/doi/10.1021/ol071038k
URL https://biblio.ugent.be/publication/383859
URL http://dx.doi.org/10.1021/ol071038k
URL https://academic.microsoft.com/#/detail/2049917615
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Access Right Open Access
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Author Freija De Vleeschouwer, 0000-0003-0563-1509
Author Speybroeck, V.
Author Waroquier, M.
Author Paul Geerlings
Author Frank De Proft
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Collected From ORCID; figshare; Datacite; Crossref; Microsoft Academic Graph
Hosted By Organic Letters; figshare
Journal Organic Letters, 9, null
Publication Date 2016-02-29
Publisher American Chemical Society (ACS)
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Language Undetermined
Resource Type Other literature type; Article
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::7d6aac064f1033e308d2859de1b2d6fc
Author jsonws_user
Last Updated 23 December 2020, 13:09 (CET)
Created 23 December 2020, 13:09 (CET)