Direct Ruthenium Catalyzed C-C Coupling of Ethanol: Diene Hydro-Hydroxyethylation to Form All Carbon Quaternary Centers

Under ruthenium-catalyzed transfer hydrogenation conditions, direct C−C coupling of ethanol and 2-substituted dienes occurs to furnish products of hydro-hydroxyethylation: anti-configured neopentyl homoallylic alcohols. Identical adducts are generated from acetaldehyde under related conditions employing isopropanol as reductant.

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PID pmc:PMC2884076
PID https://www.doi.org/10.1021/ol101077v
PID pmid:20491487
PID https://www.doi.org/10.1021/ol101077v.s001
URL https://pubs.acs.org/doi/10.1021/ol101077v
URL https://europepmc.org/articles/PMC2884076/
URL https://academic.microsoft.com/#/detail/2056001406
URL http://dx.doi.org/10.1021/ol101077v
URL https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2884076/
URL http://europepmc.org/articles/pmc2884076?pdf=render
URL https://pubs.acs.org/doi/pdf/10.1021/ol101077v
URL https://researchers.dellmed.utexas.edu/en/publications/direct-ruthenium-catalyzed-c-c-coupling-of-ethanol-diene-hydro-hy
URL https://dx.doi.org/10.1021/ol101077v
URL https://core.ac.uk/display/152974855
URL https://figshare.com/articles/journal_contribution/Direct_Ruthenium_Catalyzed_C_C_Coupling_of_Ethanol_Diene_Hydro_hydroxyethylation_To_Form_All_Carbon_Quaternary_Centers/2759806
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Access Right Open Access
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Author Han Hoon
Author Krische Michael J.
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Collected From Europe PubMed Central; PubMed Central; UnpayWall; figshare; Crossref; Microsoft Academic Graph
Hosted By Europe PubMed Central; Organic Letters; figshare
Publication Date 2010-06-18
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Language English
Resource Type Other literature type; Article; UNKNOWN
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::20549b45ffa0a79fc2eb4d76288071e1
Author jsonws_user
Last Updated 21 December 2020, 20:34 (CET)
Created 21 December 2020, 20:34 (CET)