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Tunability of Supramolecular Kagome Lattices of Magnetic Phthalocyanines Usin...
Self-assembly of various phthalocyanine (Pc) molecules and a derivative on an epitaxial graphene monolayer (MG) has been investigated by means of in situ ultrahigh vacuum... -
Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic F...
The impact of modest, industrially accessible pressures (0−1.2 GPa) on the structure and porosity of the zeolitic imidazolate framework Zn(2-methylimidazole)2, ZIF-8, was... -
Rational Design of Cavitand Receptors for Mass Sensors
This Communication describes a rational approach to the fabrication of selective mass sensors, using multiple hydrogen-bonding type interactions encoded in a single cavitand... -
Total Synthesis of (±)-Chartelline C
The first total synthesis of (±)-chartelline C in a concise 10-step sequence is reported. Highlights of the completion of this decades-old puzzle include (1) chemo- and... -
Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Fra...
Gold nanoparticles (NPs) were deposited to a zeolite-type metal−organic framework (MOF) by a simple solid grinding method. A catalyst, Au@ZIF-8, represents the first example of... -
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen ...
Highly porous and robust metal−organic frameworks (MOFs) were constructed based on aromatics-rich octa-carboxylate ligands and copper paddle-wheel building units. Each... -
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuIIwith Virtual...
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuII with Virtually Decoupled Fluorophore and Receptor Units -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Responsive Periodic Mesoporous Polydiacetylene/Silica Nanocomposites
Responsive PMO materials have been synthesized through co-assembly of bridged diacetylenic silsesquioxane and surfactant. The spatially defined polydiacetylenic component,... -
Intermolecular C−H Bond Activation Reactions Promoted by Transient Titanium A...
The neopentylidene−neopentyl complex (PNP)TiCHtBu(CH2tBu) (2; PNP- = N[2-P(CHMe2)2-4-methylphenyl]2), prepared from the precursor (PNP)TiCHtBu(OTf) (1) and LiCH2tBu, extrudes... -
Metal Carbene-Promoted Sequential Transformations for the Enantioselective Sy...
A two-step, three-component coupling of an alkyne, enol ether, and vinyl diazoester was accomplished by use of successive metal carbene-catalyzed transformations. This efficient... -
Low Temperature CO Oxidation over Unsupported Nanoporous Gold
Supported Au nanoclusters are well-known for their unusual properties in catalysis. We describe here that nanostructured porous Au made via dealloying represents a new class of... -
Isoreticular Metalation of Metal−Organic Frameworks
Sequential covalent transformation and metalation were performed on (Zn4O)3(BDC-NH2)3(BTB)4 with maintenance of crystallinity and porosity. Reaction of (Zn4O)3(BDC-NH2)3(BTB)4... -
Chiral Porous Solids Based on Lamellar Lanthanide Phosphonates
Chiral Porous Solids Based on Lamellar Lanthanide Phosphonates -
Control over Catenation in Metal−Organic Frameworks via Rational Design of th...
Metal−organic frameworks (MOFs), a hybrid class of materials comprising inorganic nodes and organic struts, have potential application in many areas due to their high surface... -
Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synt...
A new type of chiral bicycle imidazole nucleophilic catalyst was rationally designed, facilely synthesized, and successfully applied in an asymmetric Steglich rearrangement with... -
Metallothionein-Cross-Linked Hydrogels for the Selective Removal of Heavy Met...
The diverse functional repertoire of proteins promises to yield new materials with unprecedented capabilities, so long as versatile chemical methods are available to integrate... -
Photoinduced Metal-to-Metal Charge Transfer toward Single-Chain Magnet
Single-chain magnets (SCMs) that exhibit slow relaxation of their magnetization are attracting considerable attention. To tune the properties of such materials with external... -
Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Com...
Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts -
Synthesis, Characterization, and Spectroscopy of 4,7,12,15-[2.2]Paracyclophan...
This paper reports the synthesis of 4,7,12,15-tetra(4‘-dihexylaminostyryl)[2.2]paracyclophane (1), 4-(4‘-dihexylaminostyryl)-7,12,15-tri(4‘ ‘-nitrostyryl)[2.2]paracyclophane...
