Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synthesis, and Successful Application in Asymmetric Steglich Rearrangement

A new type of chiral bicycle imidazole nucleophilic catalyst was rationally designed, facilely synthesized, and successfully applied in an asymmetric Steglich rearrangement with good to excellent yield and enantioselectivity at ambient temperature. Moreover, it can be easily recycled with almost no reduction of catalytic efficiency. This is the first example for the successful chiral imidazole nucleophilic catalyst without H-bonding assistance.

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PID https://www.doi.org/10.1021/ja109069k
PID https://www.doi.org/10.1021/ja109069k.s002
URL http://dx.doi.org/10.1021/ja109069k
URL https://pubs.acs.org/doi/abs/10.1021/ja109069k
URL http://pubs.acs.org/doi/abs/10.1021/ja109069k
URL http://www.ncbi.nlm.nih.gov/pubmed/20977235
URL https://academic.microsoft.com/#/detail/2320569813
URL https://figshare.com/articles/journal_contribution/Chiral_Bicycle_Imidazole_Nucleophilic_Catalysts_Rational_Design_Facile_Synthesis_and_Successful_Application_in_Asymmetric_Steglich_Rearrangement/2712652
URL https://pubs.acs.org/doi/pdf/10.1021/ja109069k
URL https://core.ac.uk/display/152941662
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Access Right Open Access
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Author Zhang, Zhenfeng
Author Xie, Fang
Author Jia, Jia
Author Zhang, Wanbin
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Collected From Datacite; figshare; Crossref; Microsoft Academic Graph
Hosted By Journal of the American Chemical Society; figshare
Publication Date 2010-11-17
Publisher American Chemical Society (ACS)
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Language UNKNOWN
Resource Type Other literature type; Article
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::b44553fc3df0feac09cacc23d738d025
Author jsonws_user
Last Updated 24 December 2020, 14:58 (CET)
Created 24 December 2020, 14:58 (CET)