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Intermolecular Activation of Hydrocarbon C−H Bonds Initiated by the Tungsten ...
trans-CpW(NO)(CH2EMe3)(H)(PMe3) (E = C, Si) complexes can be prepared by the hydrogenation at 1 atm of the appropriate CpW(NO)(CH2EMe3)2 precursor in the presence of a slight... -
Electronic Tuning of Mg<sub>2</sub>Cu<sub>6</sub>Ga<sub>5</sub>. A Route to C...
Studies of Mg2Cu6Ga5 reveal that this compound contains incomplete Bergman clusters in its structure and shows a pseudogap and empty bonding states just above the Fermi energy... -
Novel Manganese(II) Sulfonate−Phosphonates with Dinuclear, Tetranuclear, and ...
Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S−Ph−PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II)... -
The Rate of False Positive Sequence Matches of Peptides Profiled by MALDI MS ...
In most MALDI peptide profiling cases, sequencing is required to identify peptides of interest, preferentially by using different mass spectrometry techniques. Using identical... -
Complete Mapping of the Stereochemical Course of Retentive Deprotonation/Alky...
Enantiopure amino-acid derived 1H-benzo[e][1,4]diazepin-2(3H)-ones (BZDs) undergo highly retentive deprotonation/alkylation reactions. To confirm the role of stereolabile,... -
r37980778c78--bc001d315c0aa0c725a9c9c3ca539c9b
Color tuning and switching of the solid-state luminescence of organic materials are attractive subjects for both the fundamental research and practical applications such as... -
Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of M...
Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of Methyl and Cyclic Ethers: Evidence for Reversible α-Hydrogen Migration -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
r37980778c78--63d348228602793543956144b74b0720
In this novel motif, scandium atoms define infinite parallel chains of alternate trans-face-sharing cubes and pairs of square antiprisms in which each polyhedron is also... -
Long-Range Ordered Magnet of a Charge-Transfer Ru<sub>2</sub><sup>4+</sup>/TC...
Two isostructural 2D assemblies composed of [Ru2(O2CCF3)4] and TCNQ or TCNQF4 in a 2:1 ratio were synthesized: [{Ru2(O2CCF3)4}2TCNQ]·3(p-xylene) (1b) and... -
r37980778c78--f1e1477b2cfe863e480929adb4bf7847
[{Ru(η6-p-cymene)(μ-Cl)Cl}2] and [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] react with Ph2PCH2P{NP(O)(OR)2}Ph2 (R = Et (1a), Ph (1b)) affording complexes... -
Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
Deprotonation of terminal alkynes is effected by the treatment with tBu3P and B(C6F5)3 to give [tBu3PH][PhCCB(C6F5)3] (1a) and [tBu3PH][RCCB(C6F5)3] (R = nBu 2, tBu 3, Me3Si 4,... -
Ruthenium Assisted Reversible Proton Transfer from an Aromatic Carbon to a Hy...
Ruthenium Assisted Reversible Proton Transfer from an Aromatic Carbon to a Hydride -
Insight into Substrate Binding in Shibasaki’s Li<sub>3</sub>(THF)<sub><i>n</i...
Heterobimetallic Lewis acids M3(THF)n(BINOLate)3Ln [M = Li, Na, K; Ln = lanthanide(III)] are exceptionally useful asymmetric catalysts that exhibit high levels of... -
r37980778c78--cd7a1da89ad373459434c40ca1ad511d
Three nitrosyl-dye conjugates, namely, [(Me2bpb)Ru(NO)(Resf)] (1-Resf), [(Me2bQb)Ru(NO)(Resf)] (2-Resf), and [((OMe)2bQb)Ru(NO)(Resf)] (3-Resf) have been synthesized via direct... -
Scope and Mechanism of the Iridium-Catalyzed Cleavage of Alkyl Ethers with Tr...
The cationic iridium pincer complex [(POCOP)Ir(H)(acetone)]+[B(C6F5)4]− {1, POCOP = 2,6-[OP(tBu)2]2C6H3} was found to be a highly active catalyst for the room-temperature... -
Media 1: Polarized radiance fields under a dynamic ocean surface: a three-dim...
Originally published in Applied Optics on 01 June 2009 (ao-48-16-3019) -
r37980778c78--f77dcf067d055f0dd215ece2e23b0dea
On attempting the Wolff rearrangement with an α-formyl-3-iridacyclopentanone, iridium migrates to the resulting carbene center in preference to carbon. -
<i>tcf7l2</i>, <i>mllt10/af10</i>, and <i>dot1l</i> are essential for Wnt tar...
(A–H) Representative image of BrdU incorporation into epithelial cells in the intestinal bulb of 124 hpf zebrafish embryos. BrdU staining in wild-type embryos (A) and embryos... -
1,3-Bis(3,4-dimethylene-5-methyl-2-thienyl)benzene, a Singlet Tetraradical Pr...
1,3-Bis(3,4-dimethylene-5-methyl-2-thienyl)benzene, a Singlet Tetraradical Prototype of a Quasi-Alternant Nonclassical Conducting Polymer
