4 items found

Tags: steric interference

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  • publication

    An Efficient C−H Oxidation Protocol for α-Hydroxylation of Cyclic Steroidal E...

    Various C-16 hydroxy steroids have been prepared with the aid of CrO3/Bu4NIO4. Out of the two possible reaction courses, transition state B is favored because of less steric...
  • publication

    r37980778c78--e6039210aa0fa8a9d5f9f544abe4e229

    Two polyoxophosphotungstates, [Hen][Cu(en)2(H2O)]2[Cu(en)2(H2O)2]0.5[{Cu(en)2(H2O)}2 {Cu(en)2}(P2W18O61)2]·en·nH2O (en = ethylenediamine, n = 16.35), 1, and [HenMe]2...
  • publication

    r37980778c78--eb333a2a363dcaa680033d8348a166e1

    The biological versatility of aristeromycin (carbocyclic adenosine) is limited by accompanying cytotoxicity caused ostensibly by the intracellular formation of its 5‘-nucleotide...
  • dataset

    Two Polyoxophosphotungstates Formed by Wells−Dawson Cores Linked through W−O−...

    Two polyoxophosphotungstates, [Hen][Cu(en)2(H2O)]2[Cu(en)2(H2O)2]0.5[{Cu(en)2(H2O)}2 {Cu(en)2}(P2W18O61)2]·en·nH2O (en = ethylenediamine, n = 16.35), 1, and [HenMe]2...