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r37980778c78--add99051c311035cbee6db7e3033e536
The reactions of HCl, PCl5, and a crown ether (12-crown-4 or 18-crown-6) in CHCl3 under anaerobic conditions give complexes of the superacid HPCl6: [H(12-crown-4)][PCl6 ] and... -
r37980778c78--d4f37e7d58fa593993eba62ad3404fb8
A series of 3d–4f binuclear complexes, [M(3-MeOsaltn)(MeOH)x(ac)Ln(hfac)2] (x = 0 for M = CuII, ZnII; x = 1 for M = CoII, NiII; Ln = GdIII, TbIII, DyIII, LaIII), have been... -
Crown Ether Complexes of HPCl<sub>6</sub>
The reactions of HCl, PCl5, and a crown ether (12-crown-4 or 18-crown-6) in CHCl3 under anaerobic conditions give complexes of the superacid HPCl6: [H(12-crown-4)][PCl6 ] and... -
On the Origins of Diastereoselectivity in the Alkylation of Enolates Derived ...
The stereochemical outcome observed upon alkylation of enolates derived from N-1-(1′-naphthyl)ethyl-O-tert-butylhydroxamates (chiral Weinreb amide equivalents) may be... -
r37980778c78--a3b04326871fb624ac87e691eabdf333
Despite the inherent preference for placing alkyl substituents, rather than alkoxy substituents, in equatorial positions, all-trans-hexaspiro(THF)cyclohexane strongly favors the... -
r37980778c78--94fb476d1b1564d84d5b07095f01f81e
The binding tendencies toward carboxylates of a trifurcated receptor containing three copper(II)−cyclam subunits have been investigated in pure water, through the displacement... -
Crown Ether Complexes of HPCl<sub>6</sub>
The reactions of HCl, PCl5, and a crown ether (12-crown-4 or 18-crown-6) in CHCl3 under anaerobic conditions give complexes of the superacid HPCl6: [H(12-crown-4)][PCl6 ] and... -
Multiple Isotope Effect Study of the Acid-Catalyzed Hydrolysis of Methyl Formate
Multiple isotope effects have been measured for the acid-catalyzed hydrolysis of methyl formate in 0.5 M HCl at 20 °C. The isotope effects in the present investigation include... -
r37980778c78--6b2b816ca1a52e32b35fb2dfd567c578
An enzyme preparation of Trametes hirsuta cleaves alkenes following neither the classical dioxygenase mechanism nor via a monooxygenase mechanism. A catalytic cycle for an... -
On the Origins of Diastereoselectivity in the Alkylation of Enolates Derived ...
The stereochemical outcome observed upon alkylation of enolates derived from N-1-(1′-naphthyl)ethyl-O-tert-butylhydroxamates (chiral Weinreb amide equivalents) may be... -
Highly Luminescent Poly(Methyl Methacrylate)-Incorporated Europium Complex Su...
A novel efficient antenna complex of Eu3+ [Eu(CPFHP)3(DDXPO)] supported by a highly fluorinated carbazole-substituted β-diketonate ligand, namely,... -
Highly Luminescent Poly(Methyl Methacrylate)-Incorporated Europium Complex Su...
A novel efficient antenna complex of Eu3+ [Eu(CPFHP)3(DDXPO)] supported by a highly fluorinated carbazole-substituted β-diketonate ligand, namely,...
