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r37980778c78--20784f567c3de6894cfc7c5de20ec2de
We report the use of Taft steric parameters to correlate the substituent size of a ligand with the enantiomeric ratio of a reaction. Linear free energy relationships can be... -
Palladium-Catalyzed Asymmetric Benzylic Substitution of Secondary Benzyl Carb...
A Pd/(R)-BINAP-catalyzed asymmetric benzylic substitution of secondary benzyl carbonates with amides and amines proceeds to form the corresponding optically active benzylamines...