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Tags: deuterium isotope effect keywords.Physical and Theoretical Chemistry

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    Experimental Investigation into the Mechanism of the Epoxidation of Aldehydes...

    A mechanistic study of the epoxidation of aldehydes with sulfur ylides has been carried out. The ΔG⧧ of the reaction was determined to be 22.2 kcal/mol at 298 K. A 13C kinetic...
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    Chain-Selective and Regioselective Ethylene and Styrene Dimerization Reaction...

    The cationic ruthenium hydride complex [(η6-C6H6)(PCy3)(CO)RuH]+BF4− was found to be a highly regioselective catalyst for the ethylene dimerization reaction to give 2-butene...