Near-infrared (NIR) luminescent lanthanide complexes hold great promise for practical applications, as their optical properties have several complementary advantages over...

The activity of amine bis(phenolate) Ti dibenzyl complexes in 1-hexene polymerization catalysis as a function of the phenolate substituents was investigated. Two series of Ti...

Two new classes of highly active yet air- and moisture-stable π-R-allylpalladium complexes containing bulky biaryl- and bipyrazolylphosphines with extremely broad ligand scope...

CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with...

The reaction of terbium and europium salts with the lacunary polyxometalate (POM) [As2W19O67(H2O)]14– and 2-picolinic acid (picH) affords the ternary...

We report on new anionic tridentate benzimidazole-pyridine-tetrazolate ligands that form neutral 3:1 complexes with trivalent lanthanides. The ligands are UV-absorbing...

A series of 3d–4f binuclear complexes, [M­(3-MeOsaltn)­(MeOH)x(ac)­Ln­(hfac)2] (x = 0 for M = CuII, ZnII; x = 1 for M = CoII, NiII; Ln = GdIII, TbIII, DyIII, LaIII), have been...

A series of highly volatile eight-coordinate air and moisture stable lanthanide complexes of the type [Ln­(hfaa)3(L)2] (Ln = Pr (1), Nd (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho...

We describe the syntheses, the 1H NMR studies in CD3OD and D2O as solvent, the X-ray characterization, and the luminescence properties in D2O solution of the two complexes Eu·1...

The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate...

Disilaferra- and disilaruthenacyclic complexes containing mesityl isocyanide as a ligand, 3′ and 4′, were synthesized and characterized by spectroscopy and crystallography. Both...

New Salan ligand precursors that include differently substituted phenol arms were prepared by a two-step synthetic pathway. The ligand precursors included activity-enhancing...

A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The...

Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six...

Bis­(diphenylphosphinomethyl)­phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au­(dpmp)2(CCPh)4]­(ClO4) (1), [Pt2Au­(dpmp)2(DEBf)­(CCPh)2]­(ClO4) (2),...

The reactions of a pair of enantiomers of macrocyclic nickel(II) complexes with racemic penicillamine generated two 3D hydrogen-bonded homochiral frameworks of...

The reaction of [Ni(COD)2] with stable N-heterocyclic carbenes R2Im (R2Im = 1,3-di(R)imidazole-2-ylidene; R2 = Me2, nPr2, MeiPr, iPr2) affords homoleptic [Ni(Me2Im)3] (1) or...

A density functional theory (DFT) study (BMK/6-31+G­(d)) was initiated to investigate the activation of benzylic carbon–hydrogen bonds by a molybdenum-oxo complex with a...

Selected bond lengths and angles (Å, °) for 2 and two reference complexes selected from CSD.

Bis­(diphenylphosphinomethyl)­phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au­(dpmp)2(CCPh)4]­(ClO4) (1), [Pt2Au­(dpmp)2(DEBf)­(CCPh)2]­(ClO4) (2),...