Intramolecular samarium diiodide-induced carbonyl−alkene or carbonyl−alkyne coupling reactions afforded without high dilution conditions 9- and 10-membered benzannulated...

An Especially Convenient Stereoselective Reduction of β-Hydroxy Ketones to Anti 1,3 Diols Using Samarium Diiodide†

A strategy for making amides and ureas using a polymer-supported hydroxylamine resin as a traceless linker is described. The cleavage of the linker by samarium(II) iodide is...

An Especially Convenient Stereoselective Reduction of β-Hydroxy Ketones to Anti 1,3 Diols Using Samarium Diiodide†

Intramolecular samarium diiodide-induced carbonyl−alkene or carbonyl−alkyne coupling reactions afforded without high dilution conditions 9- and 10-membered benzannulated...

10 páginas, 5 figuiras, 5 esquemas, 2 tablas.-- Supporting Information Available: General experimental procedures, 1D (1H and 13C) and 2D NMR (DQ-COSY, NOESY, HSQC, and HMBC)...