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Intermolecular Activation of Hydrocarbon C−H Bonds Initiated by the Tungsten ...
trans-CpW(NO)(CH2EMe3)(H)(PMe3) (E = C, Si) complexes can be prepared by the hydrogenation at 1 atm of the appropriate CpW(NO)(CH2EMe3)2 precursor in the presence of a slight... -
Novel Manganese(II) Sulfonate−Phosphonates with Dinuclear, Tetranuclear, and ...
Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S−Ph−PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II)... -
A Formal Total Synthesis of (+)-Zincophorin. Observation of an Unusual Urea-D...
A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an... -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantiose...
Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems -
Media 2: Time fluctuations of the phase modulation in a liquid crystal on sil...
Originally published in Optics Express on 13 October 2008 (oe-16-21-16711) -
Media 1: Weak beacon detection for air-to-ground optical wireless link establ...
Originally published in Optics Express on 01 February 2010 (oe-18-3-1841) -
r37980778c78--63d348228602793543956144b74b0720
In this novel motif, scandium atoms define infinite parallel chains of alternate trans-face-sharing cubes and pairs of square antiprisms in which each polyhedron is also... -
r37980778c78--f2d5c817238474c27419e85a80efab71
Originally published in Optics Express on 15 November 2004 (oe-12-23-5675) -
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Tr...
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co -
Long-Range Ordered Magnet of a Charge-Transfer Ru<sub>2</sub><sup>4+</sup>/TC...
Two isostructural 2D assemblies composed of [Ru2(O2CCF3)4] and TCNQ or TCNQF4 in a 2:1 ratio were synthesized: [{Ru2(O2CCF3)4}2TCNQ]·3(p-xylene) (1b) and... -
r37980778c78--f1e1477b2cfe863e480929adb4bf7847
[{Ru(η6-p-cymene)(μ-Cl)Cl}2] and [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] react with Ph2PCH2P{NP(O)(OR)2}Ph2 (R = Et (1a), Ph (1b)) affording complexes... -
Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
Deprotonation of terminal alkynes is effected by the treatment with tBu3P and B(C6F5)3 to give [tBu3PH][PhCCB(C6F5)3] (1a) and [tBu3PH][RCCB(C6F5)3] (R = nBu 2, tBu 3, Me3Si 4,... -
r37980778c78--a57187364aa6088f98ac332525f9982d
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
r37980778c78--b765924c7ac156ffcf3c89002ac8b127
Originally published in Optics Express on 16 October 2006 (oe-14-21-9716) -
r37980778c78--cd7a1da89ad373459434c40ca1ad511d
Three nitrosyl-dye conjugates, namely, [(Me2bpb)Ru(NO)(Resf)] (1-Resf), [(Me2bQb)Ru(NO)(Resf)] (2-Resf), and [((OMe)2bQb)Ru(NO)(Resf)] (3-Resf) have been synthesized via direct... -
r37980778c78--ff7c91136f7a75fe17208ab3baaf81ea
Originally published in Optics Express on 17 October 2007 (oe-15-21-14065) -
Media 2: Petal-like modes in Porro prism resonators
Originally published in Optics Express on 17 October 2007 (oe-15-21-14065) -
Structure−Reactivity Correlations for Solid-State Enantioselective Photochemi...
A prerequisite for the development of structure−reactivity correlations for photoreactive crystalline materials is to have detailed knowledge of the structural properties of the... -
Bioinspired Polyene Cyclization Promoted by Intermolecular Chiral Acetal-SnCl...
New strategies using chiral acetal or chiral mixed-acetal in the presence of Lewis acids (SnCl4 or TiCl4) to promote polyene cyclization reaction are described. Acetal-promoted...
