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r37980778c78--fb277af15837398edabe45df1c80d659
(−)-Nakadomarin A is a member of manzamine alkaloid isolated from a marine sponge and have a unique hexacyclic structure. The first total synthesis of (+)-nakadomarin A, an... -
First Total Synthesis of (±)-3-Hydroxy-11-norcytisine: Structure Confirmation...
The first total synthesis of the natural product 3-hydroxy-11-norcytisine (1), structurally related to cytisine (2), a benchmark ligand at neuronal nicotinic acetylcholine... -
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbony...
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of... -
The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid...
A stable selenenic acid was synthesized by direct oxidation of a selenol bearing a novel bowl-type substituent with H2O2, and its structure was established by X-ray... -
Metamagnetism of the First Cyano-Bridged Two-Dimensional Brick-Wall-like 4f−3...
Metamagnetism of the First Cyano-Bridged Two-Dimensional Brick-Wall-like 4f−3d Array -
The First Tetrathiafulvalene− σ−Polynitrofluorene Diads: Low HOMO−LUMO Gap, A...
The synthesis, solution redox behavior, EPR, and intramolecular charge transfer properties of novel donor−acceptor diads of TTF−σ−A type (TTF = substituted tetrathiafulvalene, σ... -
Metal-Mediated C−C Bond Making and Breaking: First Direct Evidence for a Rev...
Metal-Mediated C−C Bond Making and Breaking: First Direct Evidence for a Reversible Migration of a Benzyl Group along a Metal−Carbon Bond -
r37980778c78--810807c7e1b0833bc00e8726b9c1d0ed
The First Total Synthesis of N1999-A2: Absolute Stereochemistry and Stereochemical Implications into DNA Cleavage -
r37980778c78--5445a49109405e6d8c8609f829ac4469
New Strategies in Organic Catalysis: The First Enantioselective Organocatalytic Friedel−Crafts Alkylation -
Studies on the Total Synthesis of Streptazolin and Its Related Natural Produc...
The intramolecular Pauson−Khand reaction of 2-oxazolone derivatives with a suitable heptynyl appendage gave exclusively the corresponding... -
Microwave Assisted "Click" Chemistry for the Synthesis of Multiple Labeled-Ca...
A versatile approach has been developed for the multiple labeling of oligonucleotides. First, three linkers as a H-phosphonate monoester derivative were condensed on a... -
r37980778c78--0131168ff551e7a4fd8a86d27615f25a
A new synthesis of l-noviose (11), a sugar moiety of novobiocin, is presented. d-Gulonolactone was initially converted in a few steps to the key ester derivative 7 [1-O-benzyl... -
Construction of Eight-Membered Ether Rings by Olefin Geometry-Dependent Inter...
The first and highly stereoselective asymmetric total syntheses of eight-membered ring ether marine natural products (+)-3-(E)-pinnatifidenyne and (+)-3-(Z)-pinnatifidenyne have... -
34π Octaphyrin: First Structural Characterization of a Planar, Aromatic [1.0...
34π Octaphyrin: First Structural Characterization of a Planar, Aromatic [1.0.1.0.1.0.1.0] Octaphyrin with Inverted Heterocyclic Rings -
dedup_wf_001--e9d59187e29f1e1d9cbb831cd3a25cea
Talk at workshop "First Galaxies, First Structures" October 21-25 2019 Observatory of Paris -
The First Total Synthesis of Nakadomarin A [<i>J. Am. Chem. Soc.</i> <b>2003<...
The First Total Synthesis of Nakadomarin A [J. Am. Chem. Soc. 2003, 125, 7484−7485]. -
r37980778c78--bd7c3c431cef0a28592d9b43fdf8546e
First Demonstration of Helical Chirality in 1,4-Disubstituted (Z,Z)-1,3-Dienes: R3Si−SnR‘3-Mediated Cyclization of 1,6-Diynes -
Synthesis of the First Corrolazine: A New Member of the Porphyrinoid Family
Synthesis of the First Corrolazine: A New Member of the Porphyrinoid Family -
r37980778c78--4f233579b962a9b7b72d5464f8c22fb0
New Strategies in Organic Catalysis: The First Enantioselective Organocatalytic Friedel−Crafts Alkylation -
r37980778c78--d4b099fa30e5e5fd3a243991dc64d6e5
New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels−Alder Reaction
