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Development of the Ca−Au−In Icosahedral Quasicrystal and Two Crystalline Appr...
Electronic tuning and syntheses to gain the icosahedral quasicrystal (i-QC) (Ca14.1(2)Au44.2(8)In41.7(7), e/a = 1.98) and two approximant crystals (ACs) are reported. The tuning... -
The Rate of False Positive Sequence Matches of Peptides Profiled by MALDI MS ...
In most MALDI peptide profiling cases, sequencing is required to identify peptides of interest, preferentially by using different mass spectrometry techniques. Using identical... -
r37980778c78--6031aecb7382368938acabf96de02da3
Reaction of Dialkyltin Methoxide with Carbon Dioxide Relevant to the Mechanism of Catalytic Carbonate Synthesis -
r37980778c78--bc001d315c0aa0c725a9c9c3ca539c9b
Color tuning and switching of the solid-state luminescence of organic materials are attractive subjects for both the fundamental research and practical applications such as... -
r37980778c78--77decee5d844927dd218e6ce40954484
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantiose...
Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems -
r37980778c78--63d348228602793543956144b74b0720
In this novel motif, scandium atoms define infinite parallel chains of alternate trans-face-sharing cubes and pairs of square antiprisms in which each polyhedron is also... -
<i>ansa</i>-Metallocene-Based Cyclic[2]pyrroles
Syntheses and X-ray structural analyses of ansa-metallocene-based cyclic[2]pyrroles are described. The pyrrole units in the macrocycles adopt partial 1,2-alternate conformation... -
r37980778c78--a57187364aa6088f98ac332525f9982d
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
Noninvasive Imaging of Quantum Dots in Mice
Quantum dots having four different surface coatings were tested for use in in vivo imaging. Localization was successfully monitored by fluorescence imaging of living animals, by... -
Liquid Chromatography-Tandem and MALDI Imaging Mass Spectrometry Analyses of ...
Human tissues are an important source of biological material for the discovery of novel biomarkers. Fresh-frozen tissue could represent an ideal supply of archival material for... -
r37980778c78--b31ade386cd3e93c34ac508387b6e035
Three new luminescent cyclometalated Pt(II) complexes, [Pt(L)Cl] (1), [Pt2(L-)2] (2), and [Pt(L)(PPh3)]ClO4 (3·ClO4) (where HL = 2-phenyl-6-(1H-pyrazol-3-yl)-pyridine), were... -
Structure−Reactivity Correlations for Solid-State Enantioselective Photochemi...
A prerequisite for the development of structure−reactivity correlations for photoreactive crystalline materials is to have detailed knowledge of the structural properties of the... -
G^C Quartet A DNA-Inspired Janus-GC Heterocycle: Synthesis, Structural Anal...
G^C Quartet A DNA-Inspired Janus-GC Heterocycle: Synthesis, Structural Analysis, and Self-Organization -
Donor-Mediated Band Gap Reduction in a Homologous Series of Conjugated Polymers
A family of six donor−acceptor−donor monomers was synthesized using combinations of thiophene, 3,4-ethylenedioxythiophene and 3,4-ethylenedioxypyrrole as donor moieties, and... -
r37980778c78--e100f90c93f9df25be50135493ee3fb5
Cyclopentadienyl-free disilyl amide complexes [(Me2N)3M(SiButPh2)2]- (M = Zr, 1; Hf, 2 as [Li(THF)4]+ salts), K(18-crown-6)3/2{(Me2N)3M[(Me3Si)2Si-(CH2)2-Si(SiMe3)2]} (M = Zr,... -
α-Po Nets of Copper(II)-<i>trans</i>-1,4-Cyclohexanedicarboxylate Frameworks ...
Two novel three-dimensional frameworks Cu2(CDC)2(4,4‘-Bipy)·0.5H2CDC·1.25H2O (1) and Cu4(CDC)4(4,4‘-Bpe) (2) (CDC = trans-1,4-cyclohexanedicarboxylate; 4,4‘-Bipy =... -
r37980778c78--0e3ed717b28aa9ee7521453dd30ee1ee
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
Concise Synthesis of Novel Oxa-Bridged Compounds
A stereoselective strategy for the replacement of the 1,2-dihaloalkene bridge of tetrahalonorbornyl derivatives by an oxygen bridge involving stepwise controlled oxidation,... -
r37980778c78--d3eb2c1917d646d4d50053af29205134
The unprecedented metal-mediated transformation of an alkyne into a B,B‘ bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of...
