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Electronic Tuning of Mg<sub>2</sub>Cu<sub>6</sub>Ga<sub>5</sub>. A Route to C...
Studies of Mg2Cu6Ga5 reveal that this compound contains incomplete Bergman clusters in its structure and shows a pseudogap and empty bonding states just above the Fermi energy... -
A Formal Total Synthesis of (+)-Zincophorin. Observation of an Unusual Urea-D...
A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an... -
The First Framework Solid Composed of Vanadosilicate Clusters
In this Communication, we report the first example of a network structure composed of vanadosilicate clusters. We utilized hydrothermal conditions to synthesize a... -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
r37980778c78--33b2320384739ed76a8f1a72d6442152
Two layered vanadyl selenites with the compositions, [DABCOH2]0.5[(VIVO)(HSeO3)(SeO3)]·H2O, I, and [enH2][(VivO)2(VVO)O2(SeO3)3]-·1.25H2O, II, have been prepared by the reaction... -
r37980778c78--1267032f9b82bd6f3e84436e545df86c
C,D-ring symmetric chlorins 8 were prepared in 47−85% yield, on scales up to several hundred milligrams, by condensation of appropriately substituted bis-formyldihydrodipyrrins... -
Development of a Bioactive Paper Sensor for Detection of Neurotoxins Using Pi...
There is an increasing interest in new strategies to rapidly detect analytes of clinical and environmental interest without the need for sophisticated instrumentation. As an... -
Media 6: Review of three-dimensional holographic imaging by multiple-viewpoin...
Originally published in Applied Optics on 01 December 2009 (ao-48-34-H120) -
Highly Activated Vinyl Hydrogen in a Significantly Twisted Styrene
The novel example of a vinylic hydrogen more reactive than a benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O... -
Investigation of Gas Adsorption Performances and H<sub>2</sub> Affinities of ...
Three isomorphous porous metal-organic frameworks (MOFs; PCN-9 (Co/Fe/Mn)) with entatic metal centers have been constructed on the basis of the trigonal planar H3TATB ligand and... -
A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor G...
A pyrrolyl-based triazolophane, incorporating CH and NH donor groups, acts as a receptor for the pyrophosphate anion in chloroform solution. It shows selectivity for this... -
1,3-Bis(3,4-dimethylene-5-methyl-2-thienyl)benzene, a Singlet Tetraradical Pr...
1,3-Bis(3,4-dimethylene-5-methyl-2-thienyl)benzene, a Singlet Tetraradical Prototype of a Quasi-Alternant Nonclassical Conducting Polymer -
Sidearm Effects. Synthesis, Structural Characterization, and Reactivity of Ra...
New ether-functionalized carboranyl-indenyl hybrid ligands were prepared. They can prevent lanthanocene chlorides from ligand redistribution reactions and offer samarium(II)... -
r37980778c78--ee1aa3d805ad1606b75a22b9b0be05ff
An efficient four-step synthesis of N-BOC-5-syn- and 5-anti-carboxymethanopyrrolidines (12 and 13) and the conversion of 12 to N-BOC-methanopyrrolidine (2) are described. -
r37980778c78--857e3e72d75b6cd28e0058c646588f22
Three lanthanide-thiophenedicarboxylate hybrid compounds, [(Eu2(TDC)3(CH3OH)2·(CH3OH)] (1), [(Yb2(TDC)3(DMF)(H2O)·(CH3CH2OH)] (2), and [(Tb2(TDC)3(H2O)4] (3) (where TDC is... -
Crystal Engineering of a Permanently Porous Network Sustained Exclusively by ...
A permanently porous crystalline solid is reported that is sustained exclusively by charge-assisted H-bonds. The single-crystal X-ray structure of a layered H-bonded solid,... -
Media 12: Review of three-dimensional holographic imaging by multiple-viewpoi...
Originally published in Applied Optics on 01 December 2009 (ao-48-34-H120) -
The Crystallographic Structure of a Lewis Acid-Assisted Chiral Brønsted Acid ...
It is difficult to control the enantioselectivity in the protonation of silyl enol ethers with simple chiral Brønsted acids, mainly due to bond flexibility between the proton... -
From Oligomers to Polymer: Convergence in the HOMO−LUMO Gaps of Conjugated O...
Extrapolation of HOMO−LUMO gaps for π-conjugated oligomers at the B3LYP/6-31G(d) level of theory predict accurately (within 0.1−0.2 eV) the band gaps of conjugated polymers only... -
Media 8: Review of three-dimensional holographic imaging by multiple-viewpoin...
Originally published in Applied Optics on 01 December 2009 (ao-48-34-H120)
