The First Framework Solid Composed of Vanadosilicate Clusters

In this Communication, we report the first example of a network structure composed of vanadosilicate clusters. We utilized hydrothermal conditions to synthesize a polyoxovanadogermanate (POVG):  (C4H14N2)4[V14O44(GeOH)8]·6H2O. By substituting SiO2 for GeO2 in the synthesis, a framework solid, H4V18O46(SiO)8C4H12N2)4·(H2O)] ·4H2O, is formed in which isostructural vanadosilicate clusters are linked by five-coordinate vanadium with a (VO)O2N2 environment. The charge-compensating organic amine, 1,4-diaminobutane, in the POVG is covalently bonded to the linking vanadium polyhedra in the framework solid.

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PID https://www.doi.org/10.1021/ja0365173.s001
PID https://www.doi.org/10.1021/ja0365173.s002
URL https://figshare.com/articles/dataset/The_First_Framework_Solid_Composed_of_Vanadosilicate_Clusters/3653166
URL https://figshare.com/articles/The_First_Framework_Solid_Composed_of_Vanadosilicate_Clusters/3653166
URL https://figshare.com/articles/dataset/The_First_Framework_Solid_Composed_of_Vanadosilicate_Clusters/3653208
URL http://dx.doi.org/10.1021/ja0365173.s002
URL https://figshare.com/articles/The_First_Framework_Solid_Composed_of_Vanadosilicate_Clusters/3653208
URL http://dx.doi.org/10.1021/ja0365173.s001
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Author Tripathi, Akhilesh
Author Hughbanks, Timothy
Author Clearfield, Abraham
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Collected From figshare
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Publication Date 2016-08-18
Publisher Figshare
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Language UNKNOWN
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=dedup_wf_001::cd58527c7a9d05278a8402f0c93c06b9
Author jsonws_user
Last Updated 14 January 2021, 12:48 (CET)
Created 14 January 2021, 12:48 (CET)