-
The First Tetrathiafulvalene− σ−Polynitrofluorene Diads: Low HOMO−LUMO Gap, A...
The synthesis, solution redox behavior, EPR, and intramolecular charge transfer properties of novel donor−acceptor diads of TTF−σ−A type (TTF = substituted tetrathiafulvalene, σ... -
Metal-Mediated C−C Bond Making and Breaking: First Direct Evidence for a Rev...
Metal-Mediated C−C Bond Making and Breaking: First Direct Evidence for a Reversible Migration of a Benzyl Group along a Metal−Carbon Bond -
Studies on the Total Synthesis of Streptazolin and Its Related Natural Produc...
The intramolecular Pauson−Khand reaction of 2-oxazolone derivatives with a suitable heptynyl appendage gave exclusively the corresponding... -
r37980778c78--0131168ff551e7a4fd8a86d27615f25a
A new synthesis of l-noviose (11), a sugar moiety of novobiocin, is presented. d-Gulonolactone was initially converted in a few steps to the key ester derivative 7 [1-O-benzyl... -
Synthesis of the First Corrolazine: A New Member of the Porphyrinoid Family
Synthesis of the First Corrolazine: A New Member of the Porphyrinoid Family -
Total Synthesis of Kaitocephalin, the First Naturally Occurring AMPA/KA Recep...
Total Synthesis of Kaitocephalin, the First Naturally Occurring AMPA/KA Receptor Antagonist -
Novel Arylhydrazone-Conjugated Gold Nanoparticles with DNA-Cleaving Ability: ...
Arylhydrazones were linked onto gold nanoparticles through the poly(ethylene glycol) spacer to produce a new type of photoinduced DNA-cleaving nanomaterials with great potency. -
First Total Synthesis of (−)-Ichthyothereol and Its Acetate
The first and stereoselective total syntheses of (−)-ichthyothereol (1) and its acetate ((+)-2) were achieved by incorporation of the two chiral centers of diethyl l-tartrate.... -
Design and Structural Analysis of the First Spherical Monodendron Self-Organi...
Design and Structural Analysis of the First Spherical Monodendron Self-Organizable in a Cubic Lattice -
r37980778c78--96d50000833d2125a36ecb68dabaddea
Ellagitannin Chemistry. The First Total Synthesis of a Dimeric Ellagitannin, Coriariin A -
The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid...
: [structure: see text]. A stable selenenic acid was synthesized by direct oxidation of a selenol bearing a novel bowl-type substituent with H2O2, and its structure was... -
r37980778c78--4837b3eaddfc007e620579fb4c0698c7
First Direct Imaging of Giant Pores of the Metal−Organic Framework MIL-101 -
Metamagnetism of the First Cyano-Bridged Two-Dimensional Brick-Wall-like 4f−3...
[Gd(DMF)2(H2O)3Cr(CN)6]·H2O is the first lanthanide−transition metal array with a flat two-dimensional brick-wall-like molecular structure. The antiferromagnetic coupling...