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Bifunctional Zn<sup>II</sup>Ln<sup>III</sup> Dinuclear Complexes Combining Fi...
There were new dinuclear ZnII–LnIII complexes of general formulas [Zn(μ-L)(μ-OAc)Ln(NO3)2] (LnIII = Tb (1), Dy (2), Er (3), and Yb (4)), [Zn(μ-L)(μ-NO3)Er(NO3)2] (5),... -
Data collection and refinement statistics.
1Statistics for data from the highest-resolution shell are shown in parentheses. 2 R sym =(ΣΣ|Ihkl−〈I〉|)/(ΣIhkl), where the average intensity <I> is taken... -
Prototypes of Lanthanide(III) Agents Responsive to Enzymatic Activities in Th...
We report first prototypes of responsive lanthanide(III) complexes that can be monitored independently in three complementary imaging modalities. Through the appropriate choice... -
Syntheses and Crystal Structures of Dinuclear Complexes Containing d-Block an...
Mononuclear complexes [Re(bpym)(CO)3Cl] and [Pt(bpym)(CC−C6H4CF3)2] (bpym = 2,2‘-bipyrimidine), in which one of the bipyrimidine sites is vacant, have been used as “complex... -
Structural and Photophysical Properties of Lathanide(III) Complexes with a No...
We report here a structural and photophysical study of lanthanide complexes with the di-deprotonated form of the bibracchial lariat ether... -
Efficient Phosphodiester Hydrolysis by Luminescent Terbium(III) and Europium(...
The synthesis and structures of two new isostructural mononuclear Ln(L)(NO3)(H2O)32 complexes, with Ln = Tb (complex 1) and Eu (complex 2), which display high activity in the... -
Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes ...
New heterobinuclear lanthanide complexes with benzoxazole-substituted 8-hydroxyquinolines, [Ln(ligand)2(μ-ligand)2Na] (Ln: Yb, Lu), have been prepared and their structure... -
r37980778c78--f3b8cae855c7e67e0b1d51a19783736c
The synthesis, structure, and photoluminescence of palladium(0) and platinum(0) complexes containing biarydiphosphines, biphep (biphep =... -
Bimodal System (Luminophore and Paramagnetic Contrastophore) Derived from Ln(...
The synthesis of a new 15-membered polyaza-macrocyclic ligand L3H3, which is based on a 2,2‘-bipyridine moiety and a diethylenetriaminetriacetic acid core, is reported. The... -
Syntheses and Structures of New Luminescent Cyclometalated Palladium(II) and ...
The reactions of blue luminescent ligands 1,3-bis(7-azaindolyl)benzene (BabH), 1-bromo-3,5-bis(7-azaindolyl)benzene (Br−BabH), and 1,3,5-tris(7-azaindolyl)benzene (TabH) with... -
Polymetallic Lanthanide Complexes with PAMAM-Naphthalimide Dendritic Ligands:...
Generation 3 PAMAM dendrimers functionalized with 2,3-naphthalimide chromophoric groups on the end branches were synthesized, and the formation of Eu3+ polymetallic complexes... -
r37980778c78--9936f0987496119bf67c0d361a5ca781
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
X-ray-Excited Optical Luminescence (XEOL) and X-ray Absorption Fine Structure...
Synchrotron techniques, X-ray-excited optical luminescence (XEOL) combined with X-ray absorption fine structures (XAFS), have been used to study the electronic structure and... -
Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Dif...
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate... -
Tuning the Coordination Sphere around Highly Luminescent Lanthanide Complexes
A series of three ligands designed for the formation of water-soluble luminescent lanthanide complexes is described. All ligands are based on a... -
r37980778c78--f280fb2544b7e7cf789c97d9ecbef676
A fascinating mechanistic study of ynamido−palladium−π-allyl complexes is described that features isolation of a unique silyl ketenimine via aza-Claisen rearrangement, which can... -
Mesoporous Silica-Templated Assembly of Luminescent Polyester Particles
We report the template assembly of luminescent poly-3-hydroxybutyrate (PHB) particles doped with rare-earth complexes. The hydrophobic polymer, PHB, has been infiltrated into... -
Protease Activation of α<sub>2</sub>-Macroglobulin Modulates a Chaperone-like...
α2-Macroglobulin (α2M) is a major human blood glycoprotein best known for its ability to inhibit a broad spectrum of proteases by a unique trapping method. This action induces...
