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Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and S...
The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with... -
Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...
The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular... -
Synthesis, Structural Characterization, and Readsorption Behavior of a Solid ...
Members of the new solid solution aluminum phosphite/ ethylenediphosphonate series, Al2(O3PC2H4PO3)1-x(HPO3)2x2F2·H2O (0 ≤ x ≤ 0.32), have been prepared and fully characterized.... -
A Highly Efficient Palladacycle Catalyst for Hydrophenylation of C-, N-, and ...
A new phosphine-free palladacycle catalyst 4 was prepared from benzyl oxazoline in high yield and fully characterized. With it as catalyst, hydrophenylation reactions of a wide... -
Current-Induced Metallic State in an Organic (EDT-TSF)<sub>2</sub>GaCl<sub>4<...
A newly prepared organic conductor, (EDT-TSF)2GaCl4, shows considerable nonlinear conductance in the insulating state below 20 K, and a metallic state is restored by the... -
r37980778c78--dbd8b04530ef1df58f8b67d0ec76bf55
Enantiomerically pure 1-(1Z,3E)-sulfinyl iron(0) dienols have been elaborated to bis-olefins capable of undergoing ring-closing metathesis chemistry. Using Grubbs' ruthenium... -
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocycl...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is... -
r37980778c78--8b3ce52fa3121435dd2889362c8112f3
Enantiomerically pure 1-(1Z,3E)-sulfinyl iron(0) dienols have been elaborated to bis-olefins capable of undergoing ring-closing metathesis chemistry. Using Grubbs' ruthenium... -
Redirection of Oxidation Reactions by a Polyoxomolybdate: Oxydehydrogenation...
Redirection of Oxidation Reactions by a Polyoxomolybdate: Oxydehydrogenation Instead of Oxygenation of Alkanes with tert-Butylhydroperoxide in Acetic Acid -
Catalytic Reductive Coupling of 9-Bromofluorene
The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel... -
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbony...
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of... -
Topotactic Oxidative and Reductive Control of the Structures and Properties o...
Topotactic modification, by both oxidation and reduction, of the composition, structures, and magnetic properties of the layered oxychalcogenides Sr4Mn3O7.5Cu2Ch2 (Ch = S, Se)... -
r37980778c78--6aa49dd0ac4cda71eae14d5dde9106fc
A new layered aluminophosphate, [C6N3H17][Al2(HPO4)(PO4)2] (denoted AlPO−CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the... -
Optical Resolution of (±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine as a Ch...
(±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine, prepared from benzil and ammonium acetate, was optically resolved as a chiral framework for... -
r37980778c78--0dbe15ed22d31ec802dfc5d921aebf3b
The identification of aromatic steroid hydrocarbons bearing a methyl group at positions 1, 2, 3, 4, or 6 in sediments and petroleum has been puzzling since possible steroidal... -
Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction
Inverse electron-demand aza Diels−Alder reaction of aldimine with enol ethers proceeded under the influence of a phosphoric acid diester, derived from (R)-BINOL, to give... -
Unprecedented Tunable Tetraazamacrocycles
Novel nitrogen-bridged aza[14]cyclophanes with fine-tuned cavities have been synthesized by nucleophilic aromatic substitution of 1,5-difluoro-2,4-dinitrobenzene with... -
Polybrominated Dibenzo-<i>p</i>-dioxins, Dibenzofurans, and Diphenyl Ethers i...
Human adipose samples collected in Tokyo, Japan in 1970 and 2000 were analyzed for the presence of polybrominated dibenzo-p-dioxins (PBDDs), dibenzofurans (PBDFs), and diphenyl... -
r37980778c78--e63bc64b93e734e9841b9fd1551f176b
An Icosahedral Array of Methyl Groups Supported by an Aromatic Borane Scaffold: The [closo-B12(CH3)12]2- Ion
