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Efficient Phosphodiester Hydrolysis by Luminescent Terbium(III) and Europium(...
The synthesis and structures of two new isostructural mononuclear Ln(L)(NO3)(H2O)32 complexes, with Ln = Tb (complex 1) and Eu (complex 2), which display high activity in the... -
Enantioselective Epoxidation of Alkenes Catalyzed by 2-Fluoro-<i>N</i>-Carbet...
Several α-substituted N-carbethoxytropinones have been evaluated as catalysts for asymmetric epoxidation of alkenes with Oxone, via a dioxirane intermediate.... -
r37980778c78--c3433d284193e5b623548503abb6a8ca
The pendant amino groups in isoreticular metal−organic framework-3 (IRMOF-3) were subjected to postsynthetic modification with 10 linear alkyl anhydrides (O(CO(CH2)nCH3)2 (where... -
Practical Asymmetric Conjugate Alkynylation of Meldrum’s Acid-Derived Accepto...
Practical Asymmetric Conjugate Alkynylation of Meldrum’s Acid-Derived Acceptors: Access to Chiral β-Alkynyl Acids -
Bis-(2,5-diphenylphospholanes) with sp<sup>2</sup> Carbon Linkers: Synthesis...
Four chiral diphosphine ligands consisting of bis(2,5-diphenylphospholan-1-yl) groups connected by the sp2 carbon linkers 2,3-quinoxaline ((S,S)-Ph-Quinox), 2,3-pyrazine... -
Pore Space Partition and Charge Separation in Cage-within-Cage Indium−Organic...
The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous... -
Asymmetric Crystallization of an Achiral Lariat-type Macrocyclic Compound
The first example of a macrocyclic lariat-type compound 3, which, despite being achiral in solution, undergoes asymmetric crystallization and enantiomeric excess, was observed... -
r37980778c78--5bc28cf27041be34030e5019a8847322
The redox properties of Fe and Zn complexes coordinated by an α-diimine based N4-macrocyclic ligand (TIM) have been examined using spectroscopic methods and density functional... -
Two Polyoxophosphotungstates Formed by Wells−Dawson Cores Linked through W−O−...
Two polyoxophosphotungstates, [Hen][Cu(en)2(H2O)]2[Cu(en)2(H2O)2]0.5[{Cu(en)2(H2O)}2 {Cu(en)2}(P2W18O61)2]·en·nH2O (en = ethylenediamine, n = 16.35), 1, and [HenMe]2... -
r37980778c78--9874ce5ce8c615b42746a2478c130076
Following a critical analysis of the dioxygenase literature and injection of the insights therein into the development of new dioxygenase catalysts, two new, of four total...
