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Synthesis and Structure of Sr<sub>3</sub>GaN<sub>3</sub> and Sr<sub>6</sub>Ga...
Two new strontium gallium nitrides were obtained as single crystals by reaction in molten Na. Black Sr3GaN3 is isostructural with its transition metal analogues, Sr3MnN3,... -
r37980778c78--f1e1477b2cfe863e480929adb4bf7847
[{Ru(η6-p-cymene)(μ-Cl)Cl}2] and [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] react with Ph2PCH2P{NP(O)(OR)2}Ph2 (R = Et (1a), Ph (1b)) affording complexes... -
Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
Deprotonation of terminal alkynes is effected by the treatment with tBu3P and B(C6F5)3 to give [tBu3PH][PhCCB(C6F5)3] (1a) and [tBu3PH][RCCB(C6F5)3] (R = nBu 2, tBu 3, Me3Si 4,... -
Combination Chemistry of Hexa-Copper-Substituted Polyoxometalates Driven by t...
Reaction of CuCl2·2H2O and trivacant Keggin polyoxoanion Na9[A-α-PW9O34]·7H2O in the presence of ethylene-diamine/1,2-diaminopropane (en/enMe) under hydrothermal conditions led... -
r37980778c78--dbd8b04530ef1df58f8b67d0ec76bf55
Enantiomerically pure 1-(1Z,3E)-sulfinyl iron(0) dienols have been elaborated to bis-olefins capable of undergoing ring-closing metathesis chemistry. Using Grubbs' ruthenium... -
Amino acid sequence similarities between putative TSV proteins and those of o...
Amino acid sequence similarities between putative TSV proteins and those of other polyomaviruses. -
r37980778c78--5920e11e67397bcd3e5b93ea22fc3268
Treatment of the bis(iminobenzyl)pyridine chelate Schiff-base ligand 8 (ligPh) with FeCl2 or CoCl2 yielded the corresponding (ligPh)MCl2 complexes 9 (Fe) and 10 (Co). The... -
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocycl...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is... -
r37980778c78--8b3ce52fa3121435dd2889362c8112f3
Enantiomerically pure 1-(1Z,3E)-sulfinyl iron(0) dienols have been elaborated to bis-olefins capable of undergoing ring-closing metathesis chemistry. Using Grubbs' ruthenium... -
Catalytic Reductive Coupling of 9-Bromofluorene
The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel... -
r37980778c78--c7ce3793de8830f55f7f32851009bf95
Reaction of the Au(I) N-heterocyclic carbene (NHC) compound [Au(im(CH2py)2)2]PF6 with 2 equiv of [Cu(MeCN)4]PF6 affords the tricationic compound Au(im(CH2py)2)2(Cu(MeCN)2)23... -
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Acti...
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Active Catalyst in the Catalytic Asymmetric Aziridination Reaction -
r37980778c78--1e519d7a11474cc1aa3afbfaba6fd751
Indicated are three major domains found in the large T amino acid sequence; the J-domain (blue-shaded box), the ori DNA-binding domain (yellow-shaded box) and the helicase... -
A Series of New Manganese(II) Sulfonate-Arsonates with 2D Layer, 1D Chain, an...
Hydrothermal reactions of manganese(II) salts with o-sulfophenylarsonic acid (o-HO3S−C6H4−AsO3H2, H3L) afforded Mn3(L)2(H2O)3·H2O (1) with a layered structure. When... -
r37980778c78--9a2f95ac3c36e80bab60b8022a0765e0
Facial appearance at presentation is shown in panel A. Note the thickened skin, particularly on the nose and in the eyebrow region accompanied by central alopecia. Apart from... -
C−H vs C−C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Add...
The photochemical reaction of (C5Me5)Rh(PMe3)H2 (1) in neat acetonitrile leads to formation of the C−H activation product, (C5Me5)Rh(PMe3)(CH2CN)H (2). Thermolysis of this... -
Solid State Photochemistry: Absolute Asymmetric Photocyclization of an Achir...
Solid State Photochemistry: Absolute Asymmetric Photocyclization of an Achiral S-Aryl o-Benzoylbenzothioate to an Optically Active Phthalide Involving a Novel Phenyl Migration -
Phylogenetic analysis of known polyomaviruses and TSV.
Bayesian posterior probability trees are shown for VP1 (A), VP2 (B), large T antigen (C) and a concatenation of all three (D). Numbers at branch points represent posterior... -
Structure and Magnetism of a Spin Ladder System: (C<sub>5</sub>H<sub>9</sub>...
The crystal structure of bis(cyclopentylammonium)tetrabromocuprate(II) has been determined at room temperature and at −70 °C. The room temperature structure is orthorhombic,... -
Separating Solids: Purification of Metal-Organic Framework Materials
Separating Solids: Purification of Metal-Organic Framework Materials
