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Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and S...
The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with... -
Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...
The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular... -
r37980778c78--544c4a23cdc1d3ccd2902e0a5ef2cbf1
On the Reduction of Basic Iron Acetate: Isolation of Ferrous Species Mediating Gif-Type Oxidation of Hydrocarbons -
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbony...
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of... -
Topotactic Oxidative and Reductive Control of the Structures and Properties o...
Topotactic modification, by both oxidation and reduction, of the composition, structures, and magnetic properties of the layered oxychalcogenides Sr4Mn3O7.5Cu2Ch2 (Ch = S, Se)... -
r37980778c78--6aa49dd0ac4cda71eae14d5dde9106fc
A new layered aluminophosphate, [C6N3H17][Al2(HPO4)(PO4)2] (denoted AlPO−CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the... -
Extraordinary Atomic Mobility of Au{111} at 80 Kelvin: Effect of Styrene Adso...
We describe how the presence of styrene, a weakly adsorbed molecule, dramatically restructures the Au{111} surface at temperatures as low as 80 K. The restructuring manifests... -
Photoluminescent Layered Lanthanide Silicates
The hydrothermal synthesis and structural characterization of layered lanthanide silicates, K3[M1-aLnaSi3O8(OH)2] (M = Y3+, Tb3+; Ln = Eu3+, Er3+, Tb3+, and Gd3+), named AV-22... -
r37980778c78--e63bc64b93e734e9841b9fd1551f176b
An Icosahedral Array of Methyl Groups Supported by an Aromatic Borane Scaffold: The [closo-B12(CH3)12]2- Ion -
Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synt...
A new type of chiral bicycle imidazole nucleophilic catalyst was rationally designed, facilely synthesized, and successfully applied in an asymmetric Steglich rearrangement with... -
Chiral Porous Solids Based on Lamellar Lanthanide Phosphonates
Chiral Porous Solids Based on Lamellar Lanthanide Phosphonates -
Extraordinary Atomic Mobility of Au{111} at 80 Kelvin: Effect of Styrene Adso...
We describe how the presence of styrene, a weakly adsorbed molecule, dramatically restructures the Au{111} surface at temperatures as low as 80 K. The restructuring manifests... -
r37980778c78--c2e058e9f2f01b1c25af7d03fb1f0979
The structure of {p-C6H4[CH2OCH2C(pz)3]2[Ru(p-cymene)]2}Cl4·14H2O (pz = pyrazolyl ring) contains a one-dimensional water chain associated into an inorganic (carbon-free) layer... -
Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate
A new type of cyano-bridged Co−W bimetallic assembly, CsI[{CoII(3-cyanopyridine)2}{WV(CN)8}]·H2O was synthesized. This compound exhibited a temperature-induced phase transition... -
r37980778c78--41cb099ad288cfee553d2f049f1eb43e
Lightest Member of the Basic Carboxylate Structural Pattern: [Al3(μ3-O)(μ-O2CCF3)6(THF)3][(Me3Si)3CAl(O2CCF3)3]·C7H8 -
r37980778c78--dbabdd40798c4ede92d36e0c2378c8e2
We describe how the presence of styrene, a weakly adsorbed molecule, dramatically restructures the Au{111} surface at temperatures as low as 80 K. The restructuring manifests... -
Formation and Crystal Structure of Two-Component Host System Having Helical C...
A two-component supramolecular host system having multiple chiral points (central, axial, and helical), which can include an n-alkyl alcohol molecule, was successfully formed by... -
r37980778c78--00ec55a048f00947427f3b6796290570
Metallothionein-Cross-Linked Hydrogels for the Selective Removal of Heavy Metals from Water -
Pore Space Partition and Charge Separation in Cage-within-Cage Indium−Organic...
The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous... -
Organically Templated Linear and Layered Iron Sulfates
Linear and layered organically templated iron sulfates have been prepared under hydrothermal conditions. The linear iron sulfates, with the compositions...
