Synthetic Study of Diversifolin:  The Construction of 11-Oxabicyclo[6.2.1]undec-3-ene Core Using Ring-Closing Metathesis

Stereoselective synthesis of a potential intermediate bearing 11-oxabicyclo[6.2.1]undec-3-ene core, a common scaffold of biologically active germacrane-type sesquiterpenes, has been achieved. Synthetic features involve formal 1,3-asymmetric induction, unusual ring-closing metathesis constructing a 10-membered carbocycle system, and unique lactone transposition.

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PID https://www.doi.org/10.1021/ol7025119.s002
URL https://figshare.com/articles/journal_contribution/Synthetic_Study_of_Diversifolin_The_Construction_of_11_Oxabicyclo_6_2_1_undec_3_ene_Core_Using_Ring_Closing_Metathesis/2968012
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Author Nakamura, Tomoaki
Author Oshida, Motoko
Author Nomura, Tomoko
Author Nakazaki, Atsuo
Author Kobayashi, Susumu
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Collected From figshare
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Publication Date 2016-02-27
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Language English
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::eaa223173138f1b19b78b75e5f623ab9
Author jsonws_user
Last Updated 27 December 2020, 01:59 (CET)
Created 27 December 2020, 01:59 (CET)