r37980778c78--e1f0edabf3960e23c48cb43f26394f6c

The 1,3-asymmetric iodolactonization reaction of enantiopure α-sulfurated γ-unsaturated amides has been investigated. With sulfinyl and sulfonyl groups, a poorly stereoselective reaction was observed, whereas with a sulfanyl moiety, the diastereoselectivity can be high as 96:4. The role of the oxygen atom on the sulfur moiety is discussed.

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PID https://www.doi.org/10.1021/jo035488b.s001
URL https://figshare.com/articles/journal_contribution/Asymmetric_Induction_of_the_Iodolactonization_Reaction_of_Sulfurated_Unsaturated_Amides/3349306
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Collected From figshare
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Publication Date 2016-05-07
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::e1f0edabf3960e23c48cb43f26394f6c
Author jsonws_user
Last Updated 25 December 2020, 14:50 (CET)
Created 25 December 2020, 14:50 (CET)