Central Role of Phenanthroline Mono-<i>N</i>-oxide in the Decomposition Reactions of Tris(1,10-phenanthroline)iron(II) and -iron(III) Complexes

1,10-Phenanthroline mono-N-oxide (phenO) is a product of the decomposition of tris(1,10-phenanthroline)iron(III), Fe(phen)33+, and has a slight autocatalytic effect on the overall reaction. The mechanism is proposed to involve Fe(phen)34+ as a minor intermediate. The addition of phenO significantly influences the kinetic features of the decomposition of Fe(phen)33+ and the oxidation of Fe(phen)32+ by HSO5−. The autocatalytic decomposition explains the difficulties in the preparation of Fe(phen)33+ and may contribute to exotic kinetic phenomena studied using Fe(phen)33+/Fe(phen)33+ as a supposedly innocent indicator.

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PID https://www.doi.org/10.1021/ic902554b.s001
URL https://figshare.com/articles/journal_contribution/Central_Role_of_Phenanthroline_Mono_i_N_i_oxide_in_the_Decomposition_Reactions_of_Tris_1_10_phenanthroline_iron_II_and_iron_III_Complexes/2773054
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Access Right Open Access
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Author Bellér, Gábor
Author Lente, Gábor
Author Fábián, István
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Collected From figshare
Hosted By figshare
Publication Date 2016-02-25
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Language English
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::b90f4cf301fc720bcb972f0226b8b969
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Last Updated 26 December 2020, 15:32 (CET)
Created 26 December 2020, 15:32 (CET)