r37980778c78--adc079066ae6c0de2bbd34e27a6f395d

A unique procedure to effect a ring-expanding bromoetherification process is described, wherein tetrahydrofurans and tetrahydropyrans are smoothly transformed into 8- and 9-membered bromoethers in a regio- and stereocontrolled manner through the use of BDSB (bromodiethylsulfonium bromopentachloroantimonate). These products resemble the cores of the Laurencia C15 acetogenins. In light of the generality and effectiveness of the approach, this work provides a unique strategy for their laboratory preparation and may implicate a possible biosynthesis pathway.

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PID https://www.doi.org/10.1021/ja2069449.s002
URL https://figshare.com/articles/A_General_Strategy_for_the_Stereocontrolled_Preparation_of_Diverse_8_and_9_Membered_i_Laurencia_i_Type_Bromoethers/2603386
URL http://dx.doi.org/10.1021/ja2069449.s002
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Access Right Open Access
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Collected From figshare
Hosted By figshare
Publication Date 2016-02-22
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Language UNKNOWN
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::adc079066ae6c0de2bbd34e27a6f395d
Author jsonws_user
Last Updated 13 January 2021, 14:20 (CET)
Created 13 January 2021, 14:20 (CET)