r37980778c78--ac636cc1cfa264b6397be3183dbd16e4

A comparative study of the Au(I)-catalyzed [3,3]-sigmatropic rearrangement of propargylic esters and propargyl vinyl ethers is described. Stereochemically defined cyclopropanes are employed as mechanistic probes to provide new synthetic and theoretical data concerning the reversibility of this type of rearrangement. Factors controlling the structure−reactivity relationship of Au(I)-coordinated allenes have been examined, thereby allowing for controlled access to orthogonal reactivity.

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PID https://www.doi.org/10.1021/ja900456m.s003
URL https://figshare.com/articles/journal_contribution/Mechanistic_Studies_on_Au_I_Catalyzed_3_3_Sigmatropic_Rearrangements_using_Cyclopropane_Probes/2868409
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Collected From figshare
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Publication Date 2016-02-26
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::ac636cc1cfa264b6397be3183dbd16e4
Author jsonws_user
Last Updated 23 December 2020, 10:36 (CET)
Created 23 December 2020, 10:36 (CET)