r37980778c78--8b8a5ae28d3bb7d37a2ca2922ea2308e

The synthesis and structural characterization of 15R-, 8H-, 6H‘-, and 10H-BaMnO3-x and 9R-Ba0.875Sr0.125MnO3 is described. Neutron powder diffraction data reveal a strong preference for the location of anion vacancies within the face-shared hexagonal layers of these phases. At high anion vacancy concentrations, Mn2O9-x dimer units become prevalent. Magnetic characterization indicates antiferromagnetic order in all phases. Ordering temperatures are in the range 250 K < T < 270 K and show a dependence on the fraction of cubic layers present in the stacking sequence.

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PID https://www.doi.org/10.1021/cm062055r.s001
URL https://figshare.com/articles/journal_contribution/BaMnO_sub_3_sub_sub_sub_i_sub_x_sub_i_Revisited_A_Structural_and_Magnetic_Study/3025324
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Collected From figshare
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Publication Date 2016-02-29
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=r37980778c78::8b8a5ae28d3bb7d37a2ca2922ea2308e
Author jsonws_user
Last Updated 23 December 2020, 17:23 (CET)
Created 23 December 2020, 17:23 (CET)