Hydrogen Adsorption in an Interpenetrated Dynamic Metal−Organic Framework

A metal−organic framework Zn(NDC)(4,4‘-Bpe)0.5·xG [NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bpe = 4,4‘-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized, structurally characterized, and rationalized to be a two-interpenetrated elongated primitive cubic net. Powder X-ray diffraction and adsorption studies reveal the dynamic feature of the framework, which can take up hydrogen of about 2.0 wt % at 77 K and 40 bar and 0.3 wt % at 298 K and 65 bar.

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PID https://www.doi.org/10.1021/ic060437t.s001
URL https://figshare.com/articles/Hydrogen_Adsorption_in_an_Interpenetrated_Dynamic_Metal_Organic_Framework/3069211
URL https://figshare.com/articles/dataset/Hydrogen_Adsorption_in_an_Interpenetrated_Dynamic_Metal_Organic_Framework/3069211
URL http://dx.doi.org/10.1021/ic060437t.s001
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Author Chen, Banglin
Author Ma, Shengqian
Author Zapata, Fatima
Author Lobkovsky, Emil B.
Author Yang, Jun
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Collected From figshare
Hosted By figshare
Publication Date 2016-03-01
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Language English
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::5bb361a03766fb5356739bdf5ae21487
Author jsonws_user
Last Updated 4 January 2021, 17:26 (CET)
Created 4 January 2021, 17:26 (CET)