r37980778c78--57a8cea71350d32cfb4000e3fbaed833

An efficient and highly stereocontrolled preparation, on a large scale, of two new Wieland−Miescher-type diketones is described. The approach centers on a diastereoselective Diels−Alder reaction using a new enantiomerically pure sulfinylquinone. Mechanistic investigations of this cycloaddition on several dienes are described.

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PID https://www.doi.org/10.1021/jo060486n.s001
URL http://dx.doi.org/10.1021/jo060486n.s001
URL https://figshare.com/articles/dataset/Asymmetric_Diels_Alder_Reactions_of_a_New_Enantiomerically_Pure_Sulfinylquinone_A_Straightforward_Access_to_Functionalized_Wieland_Miescher_Ketone_Analogues_with_i_R_i_Absolute_Configuration/3074497
URL https://figshare.com/articles/Asymmetric_Diels_Alder_Reactions_of_a_New_Enantiomerically_Pure_Sulfinylquinone_A_Straightforward_Access_to_Functionalized_Wieland_Miescher_Ketone_Analogues_with_i_R_i_Absolute_Configuration/3074497
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Access Right Open Access
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Collected From figshare
Hosted By figshare
Publication Date 2016-03-01
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Language UNKNOWN
Resource Type Dataset
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Source https://science-innovation-policy.openaire.eu/search/dataset?datasetId=r37980778c78::57a8cea71350d32cfb4000e3fbaed833
Author jsonws_user
Last Updated 3 January 2021, 09:26 (CET)
Created 3 January 2021, 09:26 (CET)