Electrochemical and chemical syntheses of the hybrid organic-inorganic electroactive material formed by phosphomolybdate and polyaniline. Application as cation-insertion electrodes

We report a hybrid organic-inorganic electroactive material composed of a conducting polyaniline matrix and the phosphomolybdate anion ([PMo12O40]3-) as the active inorganic component. The material can be prepared electrochemically as thin films or chemically in the bulk, in the absence of other competing anions. The phosphomolybdate anion is anchored within the polymer matrix and not exchanged upon reduction. The material presents good conductivity and electroactivity, and it represents an example of electrodes that can take advantage of the electroactivity of zero-dimensional molecular species. A preliminary analysis of the material as a cathode in reversible lithium batteries is discussed

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PID https://www.doi.org/10.1021/cm970107u.s001
PID https://www.doi.org/10.1021/cm970107u
PID handle:10261/15493
URL http://hdl.handle.net/10261/15493
URL https://pubs.acs.org/doi/pdf/10.1021/cm970107u
URL https://figshare.com/articles/journal_contribution/Electrochemical_and_Chemical_Syntheses_of_the_Hybrid_Organic_Inorganic_Electroactive_Material_Formed_by_Phosphomolybdate_and_Polyaniline_Application_as_Cation-Insertion_Electrodes/3594867
URL https://pubs.acs.org/doi/abs/10.1021/cm970107u
URL http://dx.doi.org/10.1021/cm970107u
URL https://core.ac.uk/display/36026697
URL https://academic.microsoft.com/#/detail/2092383413
URL https://digital.csic.es/bitstream/10261/15493/3/accesoRestringido.pdf
URL https://digital.csic.es/handle/10261/15493
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Access Right Open Access
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Author Lira-Cantu, M.
Author Pedro Gomez-Romero, 0000-0002-6208-5340
Contributor Dirección General de Investigación Científica y Técnica, DGICT (España)
Contributor Comisión Interministerial de Ciencia y Tecnología, CICYT (España)
Contributor Ministerio de Educación y Ciencia (España)
Contributor Consejo Nacional de Ciencia y Tecnología (México)
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Collected From Digital.CSIC; ORCID; figshare; Crossref; Microsoft Academic Graph
Hosted By Chemistry of Materials; Digital.CSIC; figshare
Journal , ,
Publication Date 1998-02-18
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Country Spain
Description This work was supported by DGICYT (Spain, PB93-0122) and CICYT (Spain, MAT 96-1057-CO2-01). We also thank the Ministerio de Educación y Ciencia (Spain, MEC-AECI) and CONACYT (Mexico) for a predoctoral fellowship awarded to M.L.C. We thank Dr. S. Borros and I. Folch for their help in performing GPC analysis.
Description Peer reviewed
Format image/jpeg; 579917 bytes
Language UNKNOWN
Resource Type Other literature type; Article
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::fe1d6cf9e8847c6ede43e95313504838
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Last Updated 22 December 2020, 14:50 (CET)
Created 22 December 2020, 14:50 (CET)