Symmetry Relationship and Strain-Induced Transitions between Insulating M1 and M2 and Metallic R phases of Vanadium Dioxide

The ability to synthesize VO2 in the form of single-crystalline nanobeams and nano- and microcrystals uncovered a number of previously unknown aspects of the metal−insulator transition (MIT) in this oxide. In particular, several reports demonstrated that the MIT can proceed through competition between two monoclinic (insulating) phases M1 and M2 and the tetragonal (metallic) R phase under influence of strain. The nature of such phase behavior has been not identified. Here we show that the competition between M1 and M2 phases is purely lattice-symmetry-driven. Within the framework of the Ginzburg−Landau formalism, both M phases correspond to different directions of the same four-component structural order parameter, and as a consequence, the M2 phase can appear under a small perturbation of the M1 structure such as doping or stress. We analyze the strain-controlled phase diagram of VO2 in the vicinity of the R−M2−M1 triple point using the Ginzburg−Landau formalism and identify and experimentally verify the pathways for strain-control of the transition. These insights open the door toward more systematic approaches to synthesis of VO2 nanostructures in desired phase states and to use of external fields in the control of the VO2 phase states. Additionally, we report observation of the triclinic T phase at the heterophase domain boundaries in strained quasi-two-dimensional VO2 nanoplatelets, and theoretically predict phases that have not been previously observed.

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PID https://www.doi.org/10.1021/nl1020443.s001
PID https://www.doi.org/10.1021/nl1020443
URL https://core.ac.uk/display/152943385
URL https://pubs.acs.org/doi/10.1021/nl1020443
URL https://academic.microsoft.com/#/detail/2064457041
URL http://www.ncbi.nlm.nih.gov/pubmed/20939599
URL https://pubs.acs.org/doi/pdf/10.1021/nl1020443
URL http://www.osti.gov/scitech/biblio/992537-symmetry-relationship-strain-induced-transitions-between-semiconducting-m1-m2-metallic-phases-vanadium-dioxide
URL https://figshare.com/articles/journal_contribution/Symmetry_Relationship_and_Strain_Induced_Transitions_between_Insulating_M1_and_M2_and_Metallic_R_phases_of_Vanadium_Dioxide/2714413
URL http://dx.doi.org/10.1021/nl1020443
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Access Right Open Access
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Author ilia ivanov, 0000-0002-6726-2502
Author Sergei Kalinin, 0000-0001-5354-6152
Author Alexander Tselev, 0000-0002-0098-6696
Author John Budai, 0000-0002-7444-1306
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Collected From ORCID; figshare; Datacite; Crossref; Microsoft Academic Graph
Hosted By figshare; Nano Letters
Publication Date 2010-11-10
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Language English
Resource Type Other literature type; Article
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::912d6aca832e34a4336128ea31190813
Author jsonws_user
Last Updated 26 December 2020, 17:28 (CET)
Created 26 December 2020, 17:28 (CET)