Emergence of a Single Solid Chiral State from a Nearly Racemic Amino Acid Derivative

The evolution of a single chiral solid state is reported for an amino acid derivative starting from a nearly racemic mixture of solid left- and right-handed crystals. Attrition-enhanced dissolution and recrystallization processes based on solubility considerations of the Gibbs−Thomson rule, coupled with solution-phase racemization, drive this near-equilibrium system inexorably to single chirality in the solid phase.

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PID https://www.doi.org/10.1021/ja7106349
PID urn:urn:nbn:nl:ui:22-2066/72273
PID handle:2066/72273
PID handle:11370/7d6001b9-7a85-4935-b774-c064d4d360b6
PID urn:urn:nbn:nl:ui:11-dbi/47f4a86b2cc94
PID https://www.doi.org/10.1021/ja7106349.s002
URL https://repository.ubn.ru.nl/handle/2066/72273
URL http://hdl.handle.net/2066/72273
URL https://www.narcis.nl/publication/RecordID/oai%3Apure.rug.nl%3Apublications%2F7d6001b9-7a85-4935-b774-c064d4d360b6
URL https://www.rug.nl/research/portal/en/publications/emergence-of-a-single-solid-chiral-state-from-a-nearly-racemic-amino-acid-derivative(7d6001b9-7a85-4935-b774-c064d4d360b6).html
URL https://figshare.com/articles/journal_contribution/Emergence_of_a_Single_Solid_Chiral_State_from_a_Nearly_Racemic_Amino_Acid_Derivative/2960959
URL https://www.ncbi.nlm.nih.gov/pubmed/18173274
URL https://academic.microsoft.com/#/detail/2039369009
URL https://pubs.acs.org/doi/pdf/10.1021/ja7106349
URL https://pubs.acs.org/doi/10.1021/ja7106349
URL https://www.rug.nl/research/portal/files/14468157/2008JAmChemSocNoorduin.pdf
URL https://core.ac.uk/display/92519313
URL http://dx.doi.org/10.1021/ja7106349
URL https://pure.rug.nl/ws/files/14468157/2008JAmChemSocNoorduin.pdf
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Access Right Open Access
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Author Noorduin, Wim L.
Author Izumi, Toshiko
Author Millemaggi, Alessia
Author Leeman, Michel
Author Meekes, Hugo
Author Van Enckevort, Willem J. P.
Author Kellogg, Richard M.
Author Kaptein, Bernard
Author Vlieg, Elias
Author Blackmond, Donna G.
Contributor Stratingh Institute for Chemistry
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Collected From UnpayWall; figshare; Datacite; Metis Radboud University; Crossref; NARCIS; Microsoft Academic Graph
Hosted By Journal of the American Chemical Society; figshare; Metis Radboud University; Radboud Repository; NARCIS; University of Groningen Digital Archive
Journal Journal of the American Chemical Society, 130, null
Publication Date 2016-02-27
Publisher American Chemical Society (ACS)
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Country Netherlands
Format application/pdf
Language Undetermined
Resource Type Other literature type; Article
keyword arxiv.Quantitative Biology::Biomolecules
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::8d13165fd96c5ceecd56dbec00eb5fce
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Last Updated 24 December 2020, 11:27 (CET)
Created 24 December 2020, 11:27 (CET)