Platinum(II)-Catalyzed Intermolecular [3 + 2] Cycloaddition of Propadienyl Silyl Ethers and Alkenyl Ethers

A Pt(II)-catalyzed [3 + 2] cycloaddition reaction of silyl propadienyl ethers and alkenyl ethers has been developed as the first example of the utilization of allenes as a three-carbon unit in a transition-metal-catalyzed intermolecular cycloaddition reaction. Pt(II)-containing 1,3-dipole equivalents generated by electrophilic activation of silyl propadienyl ethers using a Pt(II) catalyst reacted with various electron-rich alkenes to give synthetically useful functionalized cyclopentene derivatives in high yield with wide generality.

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PID https://www.doi.org/10.1021/ja907633b.s001
PID https://www.doi.org/10.1021/ja907633b
URL https://figshare.com/articles/journal_contribution/Platinum_II_Catalyzed_Intermolecular_3_2_Cycloaddition_of_Propadienyl_Silyl_Ethers_and_Alkenyl_Ethers/2812597
URL http://www.ncbi.nlm.nih.gov/pubmed/19860447
URL http://dx.doi.org/10.1021/ja907633b
URL https://pubs.acs.org/doi/pdf/10.1021/ja907633b
URL https://pubs.acs.org/doi/10.1021/ja907633b
URL https://academic.microsoft.com/#/detail/2093350591
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Access Right Open Access
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Author Kusama, Hiroyuki
Author Ebisawa, Masaru
Author Funami, Hideaki
Author Iwasawa, Nobuharu
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Collected From figshare; Datacite; Crossref; Microsoft Academic Graph
Hosted By Journal of the American Chemical Society; figshare
Publication Date 2009-11-18
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Language English
Resource Type Other literature type; Article
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::76014716f39aaa9ea0c8082e5674c60c
Author jsonws_user
Last Updated 27 December 2020, 01:04 (CET)
Created 27 December 2020, 01:04 (CET)