Sea Breeze Modulated Volatilization of Polycyclic Aromatic Hydrocarbons from the Masnou Harbor (NW Mediterranean Sea)

9 pages, 6 tables, 3 figures.-- PMID: 12967097 [PubMed].-- Printed version published Sep 1, 2003.-- Supporting information available at: http://pubs.acs.org/doi/suppl/10.1021/es034095r

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PID https://www.doi.org/10.1021/es034095r
PID handle:10261/19519
PID https://www.doi.org/10.1021/es034095r.s001
URL https://pubs.acs.org/doi/10.1021/es034095r
URL https://figshare.com/articles/journal_contribution/Sea_Breeze_Modulated_Volatilization_of_Polycyclic_Aromatic_Hydrocarbons_from_the_Masnou_Harbor_NW_Mediterranean_Sea_/3597858
URL https://digital.csic.es/handle/10261/19519
URL https://academic.microsoft.com/#/detail/2003088576
URL https://www.ncbi.nlm.nih.gov/pubmed/12967097
URL https://dialnet.unirioja.es/servlet/articulo?codigo=777646
URL http://dx.doi.org/10.1021/es034095r
URL https://core.ac.uk/display/36030567
URL https://pubs.acs.org/doi/pdf/10.1021/es034095r
URL http://digital.csic.es/handle/10261/19519
URL http://hdl.handle.net/10261/19519
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Access Right Open Access
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Author Jordi Dachs, 0000-0002-4237-169X
Author Damià Barceló, 0000-0002-8873-0491
Author Sandra Pérez, 0000-0002-3179-3969
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Collected From Digital.CSIC; ORCID; figshare; Crossref; Microsoft Academic Graph
Hosted By Digital.CSIC; figshare; Environmental Science & Technology
Journal Environmental Science & Technology, 37, null
Publication Date 2003-07-26
Publisher American Chemical Society (ACS)
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Country Spain
Description Harbors, marinas, and coastal environments are impacted by important pollutant loadings, particularly of polycyclic aromatic hydrocarbons (PAHs). Air−water exchange is an important process driving the environmental fate of organic pollutants in aquatic environments. However, its relevance as a factor affecting the environmental fate of pollutants from harbor sediments and waters has not been properly assessed, so far, except for few coastal environments. The objective of this study is to quantify the importance of volatilization losses of PAHs from harbor sediments and waters and to study the potential role of sea breeze as a modulator of air−water exchange in coastal environments. The results show that volatilization fluxes from a medium size marina located in the NW Mediterranean sea are relatively high in comparison to those observed in other aquatic systems, particularly for the low molecular weight (MW) compounds. This is consistent with PAHs profiles observed in harbor sediments, which are depleted by the lower MW hydrocarbons. Therefore, volatilization is an important loss of low MW PAHs such as phenanthrene, methyl phenanthrene, dibenzothiophene, etc. Indeed, these PAHs have a residence time of few days in the harbor waters and sediments. Finally, the diurnal trends in volatilization fluxes mimics that of the sea breeze influenced wind speed. These results show the important role that the diurnal sea breeze exerts on the environmental fate of pollutants such as PAHs in coastal environments as a modulator of air−water exchange and as a potential driver of transport of pollutants between adjacent coastal and terrestrial environments.
Description This work was supported by the Spanish Ministry of Science and Technology (project PPQ2001-1805-CO3).
Description Peer reviewed
Format application/pdf; 22195 bytes
Language Undetermined
Resource Type Other literature type; Article
keyword Air−water exchange fluxes
system:type publication
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Source https://science-innovation-policy.openaire.eu/search/publication?articleId=dedup_wf_001::0bf3b932ab9bf03bc606638d0b744d2c
Author jsonws_user
Last Updated 26 December 2020, 15:57 (CET)
Created 26 December 2020, 15:57 (CET)