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Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and S...
The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with... -
Intermolecular Activation of Hydrocarbon C−H Bonds Initiated by the Tungsten ...
trans-CpW(NO)(CH2EMe3)(H)(PMe3) (E = C, Si) complexes can be prepared by the hydrogenation at 1 atm of the appropriate CpW(NO)(CH2EMe3)2 precursor in the presence of a slight... -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Tr...
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co -
Long-Range Ordered Magnet of a Charge-Transfer Ru<sub>2</sub><sup>4+</sup>/TC...
Two isostructural 2D assemblies composed of [Ru2(O2CCF3)4] and TCNQ or TCNQF4 in a 2:1 ratio were synthesized: [{Ru2(O2CCF3)4}2TCNQ]·3(p-xylene) (1b) and... -
Thermal Conductivities of Alternatives to CFC-11 for Foam Insulation
The present work examines the thermal conductivities of several dilute vapors which are potential alternatives to chlorofluorocarbons (CFCs) for cellular-plastic foams. Thermal... -
r37980778c78--bd0bde9a0115982ec94b687d90366bb5
The unusual luminescence behavior of the two-coordinate gold(I) carbene complex, Au{C(NHMe)2}2·0.5(acetone), is reported. Upon freezing in a liquid N2 bath, the colorless,... -
r37980778c78--0e3ed717b28aa9ee7521453dd30ee1ee
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--bc1a7e8debaa1c4e7a35f080b451a419
Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for... -
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocycl...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is... -
Room-Temperature Desulfurization of Dibenzothiophene Mediated by [(<i>i</i>-P...
Room-Temperature Desulfurization of Dibenzothiophene Mediated by [(i-Pr2PCH2)2NiH]2 -
Design and Synthesis of a Novel Series of <i>N</i>-Alkyl Isatin Acylhydrazone...
There is growing interest in using cannabinoid receptor 2 (CB2) agonists for the treatment of neuropathic pain. We have synthesized a novel series of N-alkyl isatin... -
Extraordinary Atomic Mobility of Au{111} at 80 Kelvin: Effect of Styrene Adso...
We describe how the presence of styrene, a weakly adsorbed molecule, dramatically restructures the Au{111} surface at temperatures as low as 80 K. The restructuring manifests... -
C−H Bond Activation and Subsequent C−C Bond Formation Promoted by Osmium: 2-...
Complex OsH2Cl2(PiPr3)2 promotes the C−H activation of 2-vinylpyridine and subsequently couples the activated substrate with a second 2-vinylpyridine and two acetylene... -
r37980778c78--b8a15f8c4ca1e3b1a90310c613071d8a
We demonstrate here the single-atom migration of Tb, Gd, or Ce metal from cage to cage through an intentionally induced atomic path within a carbon nanopeapod. The atomic path... -
Primers used in this study.
a Liu et al., 2011 [19]. b Ji et al., 2007 [20]. c Wei et al., 2010 [21]. d Noteborn et al., 2013 [22]. *Positions correspond to: IBDV (JQ684022), IBV (KJ425500), AEV... -
Gd<sub>5−<i>x</i></sub>Y<sub><i>x</i></sub><i>Tt</i><sub>4</sub> (<i>Tt</i> =...
A crystallographic study and theoretical assessment of the Gd/Y site preferences in the Gd5−xYxTt4 (Tt = Si, Ge) series prepared by high-temperature methods is presented. All... -
Chiral Induction in Quinoline-Derived Oligoamide Foldamers: Assignment of He...
Chiral groups attached to the end of quinoline-derived oligoamide foldamers give rise to chiral helical induction in solution. Using various chiral groups, diastereomeric... -
Ortho-Substituted Catechol Derivatives: The Effect of Intramolecular Hydroge...
This paper reports a series of chloride anion receptors containing two catechol head groups connected through their ortho-positions via a spacer chain. The linking group chosen... -
Size and Shape Selectivity of Host Networks Built Based on Tunable Secondary ...
By modulating the secondary building units derived from the primary building units, N-acylsalicylhydrazides (H3xshz), we have been able to construct isostructural but tunable...
