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A Formal Total Synthesis of (+)-Zincophorin. Observation of an Unusual Urea-D...
A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an... -
Synthesis and Structure of Sr<sub>3</sub>GaN<sub>3</sub> and Sr<sub>6</sub>Ga...
Two new strontium gallium nitrides were obtained as single crystals by reaction in molten Na. Black Sr3GaN3 is isostructural with its transition metal analogues, Sr3MnN3,... -
r37980778c78--46e4d90fb23c5fcfd6de4a18cce13edf
The mechanistic details of the Meerwein−Schmidt−Ponndorf−Verley (MSPV) reduction of ketones to the corresponding alcohols were investigated both experimentally and... -
r37980778c78--6031aecb7382368938acabf96de02da3
Reaction of Dialkyltin Methoxide with Carbon Dioxide Relevant to the Mechanism of Catalytic Carbonate Synthesis -
r37980778c78--bc001d315c0aa0c725a9c9c3ca539c9b
Color tuning and switching of the solid-state luminescence of organic materials are attractive subjects for both the fundamental research and practical applications such as... -
r37980778c78--77decee5d844927dd218e6ce40954484
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Quantitation of Twelve Metals in Tequila and Mezcal Spirits as Authenticity P...
In this paper the differentiation of silver, gold, aged and extra-aged tequila and mezcal has been carried out according to their metal content. Aluminum, barium, calcium,... -
Media 1: Transparent organic light-emitting devices with LiF/Mg:Ag cathode
Originally published in Optics Express on 07 February 2005 (oe-13-3-937) -
Generation of <i>Capn9<sup>−/−</sup></i> mice.
(A) Schematic representation of the targeting vector and WT and knock-out (KO) alleles of mouse Capn9. Exons 2 to 9 are indicated by black boxes with exon numbers. The probes... -
Dinuclear Catecholate Helicates: Their Inversion Mechanism
Dinuclear Catecholate Helicates: Their Inversion Mechanism -
r37980778c78--f37afb20a9754641d78d525665d2c681
The reactions of isolable dialkylsilylene 2,2,5,5-tetrakis(trimethylsilyl)-1-silacyclopentane-1,1-diyl with different types of ketones such as adamantanone, acetone,... -
r37980778c78--bc1a7e8debaa1c4e7a35f080b451a419
Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for... -
1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant: Sy...
1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines,... -
Efficient Route for Cyclic Olefin Polymerization: Nonchelated Monodentate Be...
We developed a series of nonchelated monodentate benzimidazole nickel complexes, bis[2-(2,6-difluorophenyl)-1H-benzimidazole]nickel(II) dibromide (1),... -
Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Dif...
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
Multiple Coordination Geometries Supported by Methylene-Linked Guanidines
The methylene-linked bicyclic guanidine based on the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) framework provides a versatile platform able to support... -
r37980778c78--0f5ca9465cd716eb853ff1e1d54afccc
A kinetic model for the oxidation of mixtures of n-heptane/iso-octane, the primary reference fuels for octane rating in spark-ignited internal combustion engines, has been... -
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic ...
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks -
Fluidic Timers for Time-Dependent, Point-of-Care Assays on Paper
This article describes an integrated approach to tracking the end point of a time-based assay that is conducted on an analytical device made out of paper. The timing mechanism...
