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Picosecond Photoreduction of Inducible Nitric Oxide Synthase by Rhenium(I)−Di...
In a continuing effort to unravel mechanistic questions associated with metalloenzymes, we are developing methods for rapid delivery of electrons to deeply buried active sites.... -
Enantioselective Total Syntheses of Ircinal A and Related Manzamine Alkaloids
Enantioselective Total Syntheses of Ircinal A and Related Manzamine Alkaloids -
NMR, Mass Spectrometry and Chemical Evidence Reveal a Different Chemical Stru...
Methanobactin (mb) is a small copper-binding peptide produced by methanotrophic bacteria and is intimately involved in both their copper metabolism and their role in the global... -
Construction of Hydrolytically-Degradable Thin Films via Layer-by-Layer Depos...
Hydrolytically degradable, multilayered films ranging from 10 to 100 nm have been constructed by the layer-by-layer deposition of degradable polycations and oppositely charged... -
The Collapse of Nanobubbles in Water
We use molecular dynamics to simulate the collapse of nanobubbles in water and show that the macroscopic description holds down to the nanometer size. We further give a... -
Rational Fine-Tuning of the Redox Potentials in Chemically Synthesized Rubred...
Rational Fine-Tuning of the Redox Potentials in Chemically Synthesized Rubredoxins -
Chemical Degradation of Drinking Water Disinfection Byproducts by Millimeter-...
The candidature of Fe−Si and Mg−Al alloys at millimeter-scale particle sizes for chemical degradation of disinfection byproducts (DBPs) in drinking water systems was... -
Organocatalytic Asymmetric Vinylogous α-Ketol Rearrangement: Enantioselective...
The catalytic enantioselective synthesis of all-carbon quaternary stereogenic centers in spirocyclic diketones has been achieved for the first time by an unprecedented... -
Topotactic oxidative and reductive control of the structures and properties o...
Topotactic modification, by both oxidation and reduction, of the composition, structures, and magnetic properties of the layered oxychalcogenides Sr4Mn3O7.5Cu2Ch2 (Ch = S, Se)... -
Evidence for Environmentally Coupled Hydrogen Tunneling during Dihydrofolate ...
Hydride transfer during catalysis by dihydrofolate reductase from Thermotoga maritima has been studied by stopped flow spectroscopy. The reduction of dihydrofolate by NADPH... -
Length-Dependent Convergence and Saturation Behavior of Electrochemical, Line...
The syntheses of trans-[Ru{4,4′-CCC6H2[2,5-(OEt)2]CCC6H4NO2}Cl(dppm)2] (19), trans-[Ru{4,4′,4′′-CCC6H4CCC6H2[2,5-(OEt)2]CCC6H4NO2}Cl(dppm)2] (20),... -
Oxygenation of Nitrogen-Coordinated Palladium(0): Synthetic, Structural, and...
Oxygenation of Nitrogen-Coordinated Palladium(0): Synthetic, Structural, and Mechanistic Studies and Implications for Aerobic Oxidation Catalysis -
Retention Stereochemistry of Thermal 1,3-Silyl Migration in Allylsilanes
Retention Stereochemistry of Thermal 1,3-Silyl Migration in Allylsilanes -
Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction
Inverse electron-demand aza Diels−Alder reaction of aldimine with enol ethers proceeded under the influence of a phosphoric acid diester, derived from (R)-BINOL, to give... -
Isolation and Characterization of a Novel Product, 2‘-Deoxyoxanosine, from 2‘...
Isolation and Characterization of a Novel Product, 2‘-Deoxyoxanosine, from 2‘-Deoxyguanosine, Oligodeoxynucleotide, and Calf Thymus DNA Treated by Nitrous Acid and Nitric Oxide -
Indium Tin Oxide Nanoparticles with Compositionally Tunable Surface Plasmon R...
Here we report the synthesis of conducting indium tin oxide (ITO) nanoparticles (NPs) and their surface plasmon resonance (SPR) properties. The SPR peaks of the ITO NPs can be... -
Can Ring Strain Be Realized in Momentum Space?
An increased electron momentum density (EMD) at low momentum is proposed to be an indicator of ring strain, with the nature of the function tending toward a maximum. A p-space... -
Substituent Effects in Cation/π Interactions and Electrostatic Potentials abo...
Substituent effects in cation/π interactions have been examined using the M05-2X DFT functional and CCSD(T) paired with triple-ζ-quality basis sets. In contrast to popular,... -
Redox-Linked Structural Changes in Ribonucleotide Reductase
Ribonucleotide reductase (RNR) catalyzes the reduction of ribonucleotides to deoxyribonucleotides.1–3 Class I RNRs are composed of a 1:1 complex of two homodimeric proteins, α2... -
An All-Inorganic, Polyoxometalate-Based Catechol Dioxygenase That Exhibits >1...
Following a critical analysis of the dioxygenase literature and injection of the insights therein into the development of new dioxygenase catalysts, two new, of four total...
